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The molar ionic strength, I, of a solution is a function of the concentration of all ions present in that solution. [3]= = where one half is because we are including both cations and anions, c i is the molar concentration of ion i (M, mol/L), z i is the charge number of that ion, and the sum is taken over all ions in the solution.
For example, in an aqueous solution of sodium chloride, less than half of the current is carried by the positively charged sodium ions (cations) and more than half is carried by the negatively charged chloride ions (anions) because the chloride ions are able to move faster, i.e., chloride ions have higher mobility than sodium ions. The sum of ...
For most ionic compounds dissolved in water, the van 't Hoff factor is equal to the number of discrete ions in a formula unit of the substance. This is true for ideal solutions only, as occasionally ion pairing occurs in solution. At a given instant a small percentage of the ions are paired and count as a single particle.
There are three common types of chemical reaction where normality is used as a measure of reactive species in solution: In acid-base chemistry, normality is used to express the concentration of hydronium ions (H 3 O +) or hydroxide ions (OH −) in a solution. Here, 1 / f eq is an integer value. Each solute can produce one or more ...
The linearized Poisson–Boltzmann equation can be used to calculate the electrostatic potential and free energy of highly charged molecules such as tRNA in an ionic solution with different number of bound ions at varying physiological ionic strengths. It is shown that electrostatic potential depends on the charge of the molecule, while the ...
There are two main kinds of complex: compounds formed by the interaction of a metal ion with a ligand and supramolecular complexes, such as host–guest complexes and complexes of anions. The stability constant(s) provide(s) the information required to calculate the concentration(s) of the complex(es) in solution.
For multivalent ions, it is usual to consider the conductivity divided by the equivalent ion concentration in terms of equivalents per litre, where 1 equivalent is the quantity of ions that have the same amount of electric charge as 1 mol of a monovalent ion: 1 / 2 mol Ca 2+, 1 / 2 mol SO 2−
[4] [5] The Jones–Dole expression works well up to about 1 M, but at higher concentrations breaks down, as the viscosity of all solutions increase rapidly at high concentrations. The large increase in viscosity as a function of solute concentration seen in all solutions above about 1 M is the effect of a jamming transition at a high ...