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Cerium sulfide forms yellow crystalline solid of cubic syngony crystals, space group Fm3m, cell parameter a = 0.5780 nm, Z = 4, of NaCl-type structure. [citation needed] The compound melts congruently at a temperature of 2450 °C.
The γ polymorph of cerium(III) sulfide adopts a cation-deficient form of the Th 3 P 4 structure. 8 out the 9 metal positions in the Th 3 P 4 structure are occupied by cerium in γ-Ce 2 S 3, with the remainder as vacancies. This composition can be represented by the formula Ce 2.667 0.333 S 4.
Cerium nitrates also form 4:3 and 1:1 complexes with 18-crown-6 (the ratio referring to that between cerium and the crown ether). Classically CAN is a primary standard for quantitative analysis. [ 8 ] [ 9 ] Cerium(IV) salts, especially cerium(IV) sulfate , are often used as standard reagents for volumetric analysis in cerimetric titrations .
Cerium sulfide may refer to: Cerium monosulfide, CeS; Cerium(III) sulfide, Ce 2 S 3 This page was last edited on 21 January 2024, at 18:17 (UTC). Text is ...
The DHCP (double hexagonal close-packed) form β-cerium is the equilibrium structure approximately from room temperature to −150 °C. The fcc form α-cerium is stable below about −150 °C; it has a density of 8.16 g/cm 3. Other solid phases occurring only at high pressures are shown on the phase diagram.
structure of (C 5 (CH 3) 4 H) 3 Ce. Color code: green = Ce, gray = C, white = H. Organocerium chemistry is the science of organometallic compounds that contain one or more chemical bond between carbon and cerium. These compounds comprise a subset of the organolanthanides. Most organocerium compounds feature Ce(III) but some Ce(IV) derivatives ...
Cerium(III) chloride – CeCl 3; Cerium(III) fluoride – CeF 3; Cerium(III) hydroxide – Ce(OH) 3; Cerium(III) iodide – CeI 3; Cerium(III) nitrate – Ce(NO 3) 3; Cerium(III) oxide – Ce 2 O 3; Cerium(III) sulfate – Ce 2 (SO 4) 3; Cerium(III) sulfide – Ce 2 S 3; Cerium(IV) hydroxide – Ce(OH) 4; Cerium(IV) nitrate – Ce(NO 3) 4 ...
In chemistry, the double bond rule states that elements with a principal quantum number (n) greater than 2 for their valence electrons (period 3 elements and higher) tend not to form multiple bonds (e.g. double bonds and triple bonds).