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For a typical second-order reaction with rate equation = [] [], if the concentration of reactant B is constant then = [] [] = ′ [], where the pseudo–first-order rate constant ′ = []. The second-order rate equation has been reduced to a pseudo–first-order rate equation, which makes the treatment to obtain an integrated rate equation much ...
The second derivative of a function f can be used to determine the concavity of the graph of f. [2] A function whose second derivative is positive is said to be concave up (also referred to as convex), meaning that the tangent line near the point where it touches the function will lie below the graph of the function.
In numerical analysis, order of accuracy quantifies the rate of convergence of a numerical approximation of a differential equation to the exact solution. Consider u {\displaystyle u} , the exact solution to a differential equation in an appropriate normed space ( V , | | | | ) {\displaystyle (V,||\ ||)} .
For this reason, the Euler method is said to be a first-order method, while the midpoint method is second order. We can extrapolate from the above table that the step size needed to get an answer that is correct to three decimal places is approximately 0.00001, meaning that we need 400,000 steps.
In fact, however, the observed reaction rate is second-order in NO 2 and zero-order in CO, [5] with rate equation r = k[NO 2] 2. This suggests that the rate is determined by a step in which two NO 2 molecules react, with the CO molecule entering at another, faster, step. A possible mechanism in two elementary steps that explains the rate ...
For example, the second-order equation y′′ = −y can be rewritten as two first-order equations: y′ = z and z′ = −y. In this section, we describe numerical methods for IVPs, and remark that boundary value problems (BVPs) require a different set of tools. In a BVP, one defines values, or components of the solution y at more than one ...
In the zeroth-order example above, the quantity "a few" was given, but in the first-order example, the number "4" is given. A first-order approximation of a function (that is, mathematically determining a formula to fit multiple data points) will be a linear approximation, straight line with a slope: a polynomial of degree 1. For example:
The first degree polynomial equation = + is a line with slope a. A line will connect any two points, so a first degree polynomial equation is an exact fit through any two points with distinct x coordinates. If the order of the equation is increased to a second degree polynomial, the following results: