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  2. Bond convexity - Wikipedia

    en.wikipedia.org/wiki/Bond_convexity

    In finance, bond convexity is a measure of the non-linear relationship of bond prices to changes in interest rates, and is defined as the second derivative of the price of the bond with respect to interest rates (duration is the first derivative). In general, the higher the duration, the more sensitive the bond price is to the change in ...

  3. Kuhn length - Wikipedia

    en.wikipedia.org/wiki/Kuhn_length

    Bond angle. The Kuhn length is a theoretical treatment, developed by Werner Kuhn, in which a real polymer chain is considered as a collection of Kuhn segments each with a Kuhn length . Each Kuhn segment can be thought of as if they are freely jointed with each other.

  4. Bent's rule - Wikipedia

    en.wikipedia.org/wiki/Bent's_rule

    Yet, clearly the bond angles between all these molecules deviate from their ideal geometries in different ways. Bent's rule can help elucidate these apparent discrepancies. [5] [20] [21] Electronegative substituents will have more p character. [5] [20] Bond angle has a proportional relationship with s character and an inverse relationship with ...

  5. Convexity (finance) - Wikipedia

    en.wikipedia.org/wiki/Convexity_(finance)

    In practice the most significant of these is bond convexity, the second derivative of bond price with respect to interest rates. As the second derivative is the first non-linear term, and thus often the most significant, "convexity" is also used loosely to refer to non-linearities generally, including higher-order terms.

  6. Option-adjusted spread - Wikipedia

    en.wikipedia.org/wiki/Option-adjusted_spread

    This difference in convexity can also be used to explain the price differential from an MBS to a Treasury bond. However, the OAS figure is usually preferred. The discussion of the "negative convexity" and "option cost" of a bond is essentially a discussion of a single MBS feature (rate-dependent cash flows) measured in different ways.

  7. Convex curve - Wikipedia

    en.wikipedia.org/wiki/Convex_curve

    A plane curve is the image of any continuous function from an interval to the Euclidean plane.Intuitively, it is a set of points that could be traced out by a moving point. More specifically, smooth curves generally at least require that the function from the interval to the plane be continuously differentiable, and in some contexts are defined to require higher derivative

  8. Walsh diagram - Wikipedia

    en.wikipedia.org/wiki/Walsh_diagram

    For the simplest AH 2 molecular system, Walsh produced the first angular correlation diagram by plotting the ab initio orbital energy curves for the canonical molecular orbitals while changing the bond angle from 90° to 180°. As the bond angle is distorted, the energy for each of the orbitals can be followed along the lines, allowing a quick ...

  9. VSEPR theory - Wikipedia

    en.wikipedia.org/wiki/VSEPR_theory

    Shows location of unpaired electrons, bonded atoms, and bond angles. The bond angle for water is 104.5°. Valence shell electron pair repulsion ( VSEPR ) theory ( / ˈ v ɛ s p ər , v ə ˈ s ɛ p ər / VESP -ər , [ 1 ] : 410 və- SEP -ər [ 2 ] ) is a model used in chemistry to predict the geometry of individual molecules from the number of ...

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