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As a consequence, the molar mass constant remains close to but no longer exactly 1 g/mol, meaning that the mass in grams of one mole of any substance remains nearly but no longer exactly numerically equal to its average molecular mass in daltons, [30] although the relative standard uncertainty of 4.5 × 10 −10 at the time of the redefinition ...
The dalton, symbol Da, is also sometimes used as a unit of molar mass, especially in biochemistry, with the definition 1 Da = 1 g/mol, despite the fact that it is strictly a unit of mass (1 Da = 1 u = 1.660 539 068 92 (52) × 10 −27 kg, as of 2022 CODATA recommended values).
For example, water has a molar mass of 18.0153(3) g/mol, but individual water molecules have molecular masses which range between 18.010 564 6863(15) Da (1 H 2 16 O) and 22.027 7364(9) Da (2 H 2 18 O). Atomic and molecular masses are usually reported in daltons, which is defined in terms of the mass of the isotope 12 C (carbon-12).
Because a dalton, a unit commonly used to measure atomic mass, is exactly 1/12 of the mass of a carbon-12 atom, this definition of the mole entailed that the mass of one mole of a compound or element in grams was numerically equal to the average mass of one molecule or atom of the substance in daltons, and that the number of daltons in a gram ...
One dalton is equal to 1 ⁄ 12 the mass of a carbon-12 atom in its natural state. Thus, the numeric value of the atomic mass when expressed in daltons has nearly the same value as the mass number . The value of 1 unified atomic mass unit in kilograms is m u = 1.660539066 × 10 − 27 k g {\displaystyle m_{\rm {u}}=1.660539066\times 10^{-27 ...
The molar mass constant is still very close to 1 g/mol, but no longer exactly equal to it. Appendix 2 to the 9th SI Brochure states that "the molar mass of carbon 12, M(12 C), is equal to 0.012 kg⋅mol −1 within a relative standard uncertainty equal to that of the recommended value of N A h at the time this Resolution was adopted, namely 4.5 ...
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This value is then used to calculate a new approximation to A r (e), and the process repeated until the values no longer vary (given the relative uncertainty of the measurement, 2.1 × 10 −9): this happens by the fourth cycle of iterations for these results, giving A r (e) = 5.485 799 111 (12) × 10 −4 for these data.