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For a fixed mass of an ideal gas kept at a fixed temperature, pressure and volume are inversely proportional. [2] Boyle's law is a gas law, stating that the pressure and volume of a gas have an inverse relationship. If volume increases, then pressure decreases and vice versa, when the temperature is held constant.
A statement of this theorem is that any physical law can be expressed as an identity involving only dimensionless combinations (ratios or products) of the variables linked by the law (e. g., pressure and volume are linked by Boyle's Law – they are inversely proportional). If the dimensionless combinations' values changed with the systems of ...
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
Specific volume is inversely proportional to density. If the density of a substance doubles, its specific volume, as expressed in the same base units, is cut in half. If the density drops to 1/10 its former value, the specific volume, as expressed in the same base units, increases by a factor of 10.
The main feature of thermodynamic diagrams is the equivalence between the area in the diagram and energy. When air changes pressure and temperature during a process and prescribes a closed curve within the diagram the area enclosed by this curve is proportional to the energy which has been gained or released by the air.
The van der Waals equation of state may be written as (+) =where is the absolute temperature, is the pressure, is the molar volume and is the universal gas constant.Note that = /, where is the volume, and = /, where is the number of moles, is the number of particles, and is the Avogadro constant.
where is the initial density and / denotes the derivative of pressure with respect to density. The inverse of the bulk modulus gives a substance's compressibility . Generally the bulk modulus is defined at constant temperature as the isothermal bulk modulus, but can also be defined at constant entropy as the adiabatic bulk modulus.
is the static pressure [M 1 L −1 T −2], is the specific gas constant [L 2 T −2 θ −1] (287.05 J/(kg K) for air), is the density [M 1 L −3]. If the temperature is increased, but the volume kept constant, then the Knudsen number (and the mean free path) doesn't change (for an ideal gas). In this case, the density stays the same.