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The voltage (v) on the capacitor (C) changes with time as the capacitor is charged or discharged via the resistor (R) In electronics, when a capacitor is charged or discharged via a resistor, the voltage on the capacitor follows the above formula, with the half time approximately equal to 0.69 times the time constant, which is equal to the product of the resistance and the capacitance.
In thermodynamics, the reduced properties of a fluid are a set of state variables scaled by the fluid's state properties at its critical point.These dimensionless thermodynamic coordinates, taken together with a substance's compressibility factor, provide the basis for the simplest form of the theorem of corresponding states.
Haldane's decompression model is a mathematical model for decompression to sea level atmospheric pressure of divers breathing compressed air at ambient pressure that was proposed in 1908 by the Scottish physiologist, John Scott Haldane (2 May 1860 – 14/15 March 1936), [1] who was also famous for intrepid self-experimentation.
Defining equation (physical chemistry) List of electromagnetism equations; List of equations in classical mechanics; List of equations in gravitation; List of equations in nuclear and particle physics; List of equations in quantum mechanics; List of photonics equations; List of relativistic equations; Table of thermodynamic equations
Many thermodynamic equations are expressed in terms of partial derivatives. For example, the expression for the heat capacity at constant pressure is: = which is the partial derivative of the enthalpy with respect to temperature while holding pressure constant.
Theoretical chemistry requires quantities from core physics, such as time, volume, temperature, and pressure.But the highly quantitative nature of physical chemistry, in a more specialized way than core physics, uses molar amounts of substance rather than simply counting numbers; this leads to the specialized definitions in this article.
The discontinuity in , and other properties, e.g. internal energy, , and entropy,, of the substance, is called a first order phase transition. [12] [13] In order to specify the unique experimentally observed pressure, (), at which it occurs another thermodynamic condition is required, for from Fig.1 it could clearly occur for any pressure in the range .
Δp is the pressure difference between the two ends, L is the length of pipe, μ is the dynamic viscosity, Q is the volumetric flow rate, R is the pipe radius, A is the cross-sectional area of pipe. The equation does not hold close to the pipe entrance. [8]: 3 The equation fails in the limit of low viscosity, wide and/or short pipe.