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The reaction was first used by Antoine Béchamp to reduce nitronaphthalene and nitrobenzene to naphthylamine and aniline, respectively. [3] The Béchamp reduction is broadly applicable to aromatic nitro compounds. [4] [5] Aliphatic nitro compounds are however more difficult to reduce, often remaining as the hydroxylamine. Tertiary aliphatic ...
Aniline (from Portuguese anil 'indigo shrub', and -ine indicating a derived substance) [6] is an organic compound with the formula C 6 H 5 NH 2. Consisting of a phenyl group ( −C 6 H 5 ) attached to an amino group ( −NH 2 ), aniline is the simplest aromatic amine .
The aniline point measure of the ability of the base oil to act as a solvent and is determined from the temperature at which equal volumes of aniline and the base stock are soluble High aniline points (approximately 100°C or greater) imply a paraffinic base stock, while low aniline points (less than 100°C) imply a naphthenic or aromatic stock.
Hairline lowering (alternately, a scalp advancement or forehead reduction) is a surgical technique that allows an individual to have their frontal hairline advanced certain distances depending on variables such as pre-operative hairline height, scalp laxity, and patient preference. [1]
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Diphenylamine is produced by the thermal deamination of aniline over oxide catalysts: 2 C 6 H 5 NH 2 → (C 6 H 5) 2 NH + NH 3. It is a weak base, with a K b of 10 −14. With strong acids, it forms salts. For example, treatment with sulfuric acid gives the bisulfate [(C 6 H 5) 2 NH 2] + [HSO 4] − as a white or yellowish powder with m.p. 123 ...
The first step of the production of MDI is the reaction of aniline and formaldehyde, using hydrochloric acid as a catalyst to produce 4,4'-Methylenedianiline and other diamine precursors, as well as their corresponding polyamines:
Sulfanilic acid can be produced by sulfonation of aniline with concentrated sulfuric acid. [5] This proceeds via phenylsulfamic acid; a zwitterion with a N-S bond. Eugen Bamberger originally proposed a mechanism involving a series of intramolecular rearrangements, with phenylsulfamic acid forming orthanilic acid, which rearranged to sulfanilic acid on heating.