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Conductivity or specific conductance of an electrolyte solution is a measure of its ability to conduct electricity. The SI unit of conductivity is siemens per meter (S/m). Conductivity measurements are used routinely in many industrial and environmental applications as a fast, inexpensive and reliable way of measuring the ionic content in a ...
For strong electrolytes, such as salts, strong acids and strong bases, the molar conductivity depends only weakly on concentration. On dilution there is a regular increase in the molar conductivity of strong electrolyte, due to the decrease in solute–solute interaction. Based on experimental data Friedrich Kohlrausch (around the year 1900 ...
Strong electrolyte. In chemistry, a strong electrolyte is a solute that completely, or almost completely, ionizes or dissociates in a solution. These ions are good conductors of electric current in the solution. Originally, a "strong electrolyte" was defined as a chemical compound that, when in aqueous solution, is a good conductor of electricity.
The Debye–Hückel theory was proposed by Peter Debye and Erich Hückel as a theoretical explanation for departures from ideality in solutions of electrolytes and plasmas. [1] It is a linearized Poisson–Boltzmann model, which assumes an extremely simplified model of electrolyte solution but nevertheless gave accurate predictions of mean activity coefficients for ions in dilute solution.
Conductometry. Conductometry is a measurement of electrolytic conductivity to monitor a progress of chemical reaction. Conductometry has notable application in analytical chemistry, where conductometric titration is a standard technique. In usual analytical chemistry practice, the term conductometry is used as a synonym of conductometric ...
Law of dilution. Wilhelm Ostwald ’s dilution law is a relationship proposed in 1888 [1] between the dissociation constant Kd and the degree of dissociation α of a weak electrolyte. The law takes the form [2] Where the square brackets denote concentration, and c0 is the total concentration of electrolyte. Using , where is the molar ...
Electrolyte. An electrolyte is a substance that conducts electricity through the movement of ions, but not through the movement of electrons. [1][2][3] This includes most soluble salts, acids, and bases, dissolved in a polar solvent like water. Upon dissolving, the substance separates into cations and anions, which disperse uniformly throughout ...
The higher the percentage, the stronger the electrolyte. Thus, even if a substance is not very soluble, but does dissociate completely into ions, the substance is defined as a strong electrolyte. Similar logic applies to a weak electrolyte. Strong acids and bases are good examples, such as HCl and H 2 SO 4. These will all exist as ions in an ...