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Cyclopentadiene is a highly reactive diene in the Diels–Alder reaction because minimal distortion of the diene is required to achieve the envelope geometry of the transition state compared to other dienes. [11] Famously, cyclopentadiene dimerizes. The conversion occurs in hours at room temperature, but the monomer can be stored for days at ...
The Gmelin rare earths handbook lists 1522 °C and 1550 °C as two melting points given in the literature, the most recent reference [Handbook on the chemistry and physics of rare earths, vol.12 (1989)] is given with 1529 °C.
Melting point: −135 °C (−211 °F; 138 K) Boiling point: ... It can also be produced by the catalytic hydrogenation of cyclopentadiene. [6] Reactions
Melting points (in blue) and boiling points (in pink) of the first eight carboxylic acids (°C). For most substances, melting and freezing points are approximately equal. For example, the melting and freezing points of mercury is 234.32 kelvins (−38.83 °C; −37.89 °F). [2]
The basis for this reactivity is the weakness of doubly allylic C-H bonds, leading to pentadienyl radicals. A range of reactions with oxygen occur. A range of reactions with oxygen occur. Products include fatty acid hydroperoxides , epoxy-hydroxy polyunsaturated fatty acids, jasmonates , divinylether fatty acids , and leaf aldehydes .
A famous example of this type of complex is ferrocene (FeCp 2), which has many analogues for other metals, such as chromocene (CrCp 2), cobaltocene (CoCp 2), and nickelocene (NiCp 2). When the Cp rings are mutually parallel the compound is known as a sandwich complex. This area of organometallic chemistry was first developed in the 1950s.
Magnesocene is a white solid at room temperature. [1] It has a melting point of 176 °C, though at atmospheric pressures it sublimes at 100 °C. [1] Unlike ferrocene, magnesocene displays slight dissociation and subsequent ion association in polar, electron-donating solvents (such as ether and THF).
Cyclopentadienylcobalt dicarbonyl is an organocobalt compound with formula (C 5 H 5)Co(CO) 2, abbreviated CpCo(CO) 2.It is an example of a half-sandwich complex.It is a dark red air sensitive liquid.