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Chlorine is a chemical element; it has symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is a yellow-green gas at room temperature.
Inorganic chloramines are produced by the reaction of ammonia and hypochlorous acid or chlorine. An urban legend claims that mixing household bleach (aqueous sodium hypochlorite) with ammonia-based cleaners releases chlorine gas or mustard gas; in reality, the gas produced by the reaction is a mixture of inorganic chloramines.
Percent active chlorine values have now virtually replaced the older system of chlorometric degrees: 1% active chlorine is equivalent to 3.16 °Cl. Taking the (reasonable) assumption that all active chlorine present in a liquid bleach is in the form of hypochlorite ions, 1% active chlorine is equivalent to 0.141 mol/kg ClO − (0.141 mol/L if ...
Chlorine can be manufactured by the electrolysis of a sodium chloride solution , which is known as the Chloralkali process. The production of chlorine results in the co-products caustic soda (sodium hydroxide, NaOH) and hydrogen gas (H 2). These two products, as well as chlorine itself, are highly reactive.
Chlorine perchlorate is a chemical compound with the formula Cl 2 O 4. This chlorine oxide is an asymmetric oxide, with one chlorine atom in +1 oxidation state and the other +7, with proper formula ClOClO 3. It is produced by the photodimerization of chlorine dioxide (ClO 2) at room temperature by 436 nm ultraviolet light: [2] [3] [4] 2ClO 2 ...
In chemistry, hypochlorite, or chloroxide is an anion with the chemical formula ClO −. It combines with a number of cations to form hypochlorite salts. Common examples include sodium hypochlorite (household bleach) and calcium hypochlorite (a component of bleaching powder, swimming pool "chlorine"). [1] The Cl-O distance in ClO − is 1.69 Å ...
In swimming pools, chloramines are formed by the reaction of free chlorine with amine groups present in organic substances, mainly those biological in origin (e.g., urea in sweat and urine). Chloramines, compared to free chlorine, are both less effective as a sanitizer and, if not managed correctly, more irritating to the eyes of swimmers.
The chlorite ion adopts a bent molecular geometry, due to the effects of the lone pairs on the chlorine atom, with an O–Cl–O bond angle of 111° and Cl–O bond lengths of 156 pm. [1] Chlorite is the strongest oxidiser of the chlorine oxyanions on the basis of standard half cell potentials.
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