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Characteristic X-rays are emitted when outer-shell electrons fill a vacancy in the inner shell of an atom, releasing X-rays in a pattern that is "characteristic" to each element. Characteristic X-rays were discovered by Charles Glover Barkla in 1909, [ 1 ] who later won the Nobel Prize in Physics for his discovery in 1917.
The continuous X-spectrum emitted from the tube irradiates the specimen and excites the characteristic spectral X-ray lines in the specimen. Each of the 92 elements emits a characteristic spectrum. Unlike the optical spectrum, the X-ray spectrum is quite simple.
The former is due to bremsstrahlung, while the latter are characteristic X-rays associated with the atoms in the target. For this reason, bremsstrahlung in this context is also called continuous X-rays. [24] The German term itself was introduced in 1909 by Arnold Sommerfeld in order to explain the nature of the first variety of X-rays. [23]
X-rays are emitted as the electrons slow down (decelerate) in the metal. The output spectrum consists of a continuous spectrum of X-rays, with additional sharp peaks at certain energies (see graph on right). The continuous spectrum is due to bremsstrahlung, while the sharp peaks are characteristic X-rays associated with the atoms in the target.
At the much shorter wavelengths of X-rays, the lines are known as characteristic X-rays because they remain largely unchanged for a given chemical element, independent of their chemical environment. Longer wavelengths correspond to lower energies, where the infrared spectral lines include the Paschen series of hydrogen.
X-ray fluorescence (XRF) is the emission of characteristic "secondary" (or fluorescent) X-rays from a material that has been excited by being bombarded with high-energy X-rays or gamma rays.
The Siegbahn notation is used in X-ray spectroscopy to name the spectral lines that are characteristic to elements. It was introduced by Manne Siegbahn.. The characteristic lines in X-ray emission spectra correspond to atomic electronic transitions where an electron jumps down to a vacancy in one of the inner shells of an atom.
Wavelength-dispersive X-ray spectroscopy (WDXS or WDS) is a non-destructive analysis technique used to obtain elemental information about a range of materials by measuring characteristic x-rays within a small wavelength range. The technique generates a spectrum in which the peaks correspond to specific x-ray lines and elements can be easily ...