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The behavior of a thermodynamic system is summarized in the laws of Thermodynamics, which concisely are: . Zeroth law of thermodynamics; If A, B, C are thermodynamic systems such that A is in thermal equilibrium with B and B is in thermal equilibrium with C, then A is in thermal equilibrium with C.
For quasi-static and reversible processes, the first law of thermodynamics is: d U = δ Q − δ W {\displaystyle dU=\delta Q-\delta W} where δQ is the heat supplied to the system and δW is the work done by the system.
Specific volume is the volume occupied by a unit of mass of a material. [1] In many cases, the specific volume is a useful quantity to determine because, as an intensive property, it can be used to determine the complete state of a system in conjunction with another independent intensive variable. The specific volume also allows systems to be ...
In thermodynamics, Bridgman's thermodynamic equations are a basic set of thermodynamic equations, derived using a method of generating multiple thermodynamic identities involving a number of thermodynamic quantities.
The first law of thermodynamics is essentially a definition of heat, i.e. heat is the change in the internal energy of a system that is not caused by a change of the external parameters of the system. However, the second law of thermodynamics is not a defining relation for the entropy.
The properties molar internal energy, , and entropy, , defined by the first and second laws of thermodynamics, hence all thermodynamic properties of a simple compressible substance, can be specified, up to a constant of integration, by two measurable functions, a mechanical equation of state, = (,), and a constant volume specific heat, (,).
The definition of the Gibbs function is = + where H is the enthalpy defined by: = +. Taking differentials of each definition to find dH and dG, then using the fundamental thermodynamic relation (always true for reversible or irreversible processes): = where S is the entropy, V is volume, (minus sign due to reversibility, in which dU = 0: work other than pressure-volume may be done and is equal ...
Amagat's law states that the extensive volume V = Nv of a gas mixture is equal to the sum of volumes V i of the K component gases, if the temperature T and the pressure p remain the same: [1] [2] (,) = = (,). This is the experimental expression of volume as an extensive quantity.