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The Drude model of electrical conduction was proposed in 1900 [1] [2] by Paul Drude to explain the transport properties of electrons in materials (especially metals). Basically, Ohm's law was well established and stated that the current J and voltage V driving the current are related to the resistance R of the material.
In solid-state physics, the free electron model is a quantum mechanical model for the behaviour of charge carriers in a metallic solid. It was developed in 1927, [1] principally by Arnold Sommerfeld, who combined the classical Drude model with quantum mechanical Fermi–Dirac statistics and hence it is also known as the Drude–Sommerfeld model.
This intraband absorption is different from interband absorption because the excited carrier is already in an excited band, such as an electron in the conduction band or a hole in the valence band, where it is free to move. In interband absorption, the carrier starts in a fixed, nonconducting band and is excited to a conducting one.
Free electron in physics may refer to: Electron, as a free particle; Solvated electron; Charge carrier, as carriers of electric charge; Valence electron, as an outer shell electron that is associated with an atom; Valence and conduction bands, as a conduction band electron relative to the electronic band structure of a solid
Although the Drude model was fairly successful in describing the electron motion within metals, it has some erroneous aspects: it predicts the Hall coefficient with the wrong sign compared to experimental measurements, the assumed additional electronic heat capacity to the lattice heat capacity, namely per electron at elevated temperatures, is also inconsistent with experimental values, since ...
Free electron model [ edit ] After taking into account the quantum effects, as in the free electron model , the heat capacity, mean free path and average speed of electrons are modified and the proportionality constant is then corrected to π 2 3 ≈ 3.29 {\displaystyle {\frac {\pi ^{2}}{3}}\approx 3.29} , which agrees with experimental values.
An early model of electrical conduction was the Drude model, which applied kinetic theory to the electrons in a solid. By assuming that the material contains immobile positive ions and an "electron gas" of classical, non-interacting electrons, the Drude model was able to explain electrical and thermal conductivity and the Hall effect in metals ...
It can be shown that the electrons placed in these bands behave as free electrons except with a different mass, as long as their energy stays within the range of validity of the approximation above. As a result, the electron mass in models such as the Drude model must be replaced with the effective mass.