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  2. Grotthuss mechanism - Wikipedia

    en.wikipedia.org/wiki/Grotthuss_mechanism

    Protons tunnel across a series of hydrogen bonds between hydronium ions and water molecules.. The Grotthuss mechanism (also known as proton jumping) is a model for the process by which an 'excess' proton or proton defect diffuses through the hydrogen bond network of water molecules or other hydrogen-bonded liquids through the formation and concomitant cleavage of covalent bonds involving ...

  3. Split and pool synthesis - Wikipedia

    en.wikipedia.org/wiki/Split_and_pool_synthesis

    The split and pool synthesis (S&P synthesis) differs from traditional synthetic methods. The important novelty is the use of compound mixtures in the process. This is the reason of its unprecedentedly high productivity. Using the method one single chemist can make more compounds in a week than all chemists produced in the whole history of ...

  4. Quantum tunneling of water - Wikipedia

    en.wikipedia.org/wiki/Quantum_tunneling_of_water

    The quantum tunneling of water occurs when water molecules in nanochannels exhibit quantum tunneling behavior that smears out the positions of the hydrogen atoms into a pair of correlated rings. [1] In that state, the water molecules become delocalized around a ring and assume an unusual double top-like shape.

  5. Condensation reaction - Wikipedia

    en.wikipedia.org/wiki/Condensation_reaction

    The addition of the two molecules typically proceeds in a step-wise fashion to the addition product, usually in equilibrium, and with loss of a water molecule (hence the name condensation). [3] The reaction may otherwise involve the functional groups of the molecule, and is a versatile class of reactions that can occur in acidic or basic ...

  6. Single-molecule experiment - Wikipedia

    en.wikipedia.org/wiki/Single-molecule_experiment

    A single-molecule experiment is an experiment that investigates the properties of individual molecules. Single-molecule studies may be contrasted with measurements on an ensemble or bulk collection of molecules, where the individual behavior of molecules cannot be distinguished, and only average characteristics can be

  7. Water cluster - Wikipedia

    en.wikipedia.org/wiki/Water_cluster

    Detailed water models predict the occurrence of water clusters, as configurations of water molecules whose total energy is a local minimum. [6] [7] [8] Of particular interest are the cyclic clusters (H 2 O) n; these have been predicted to exist for n = 3 to 60. [9] [10] [11] At low temperatures, nearly 50% of water molecules are included in ...

  8. Chemical bonding of water - Wikipedia

    en.wikipedia.org/wiki/Chemical_bonding_of_water

    For molecules containing lone pairs, the true hybridization of these molecules depends on the amount of s and p characters of the central atom which is related to its electronegativity. "According to Bent's rule , as the substituent electronegativies increase, orbitals of greater p character will be directed towards those groups.

  9. Sol–gel process - Wikipedia

    en.wikipedia.org/wiki/Sol–gel_process

    By definition, condensation liberates a small molecule, such as water or alcohol. This type of reaction can continue to build larger and larger silicon-containing molecules by the process of polymerization. Thus, a polymer is a huge molecule (or macromolecule) formed from hundreds or thousands of units called monomers. The number of bonds that ...