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Contributing structures of the carbonate ion. In chemistry, resonance, also called mesomerism, is a way of describing bonding in certain molecules or polyatomic ions by the combination of several contributing structures (or forms, [1] also variously known as resonance structures or canonical structures) into a resonance hybrid (or hybrid structure) in valence bond theory.
In chemistry, the mesomeric effect (or resonance effect) is a property of substituents or functional groups in a chemical compound. It is defined as the polarity produced in the molecule by the interaction of two pi bonds or between a pi bond and lone pair of electrons present on an adjacent atom. [ 1 ]
As a result, enolate ions are more common than enols in both laboratory and biological chemistry. Because they are resonance hybrids of two nonequivalent forms, enolate ions can be looked at either as vinylic alkoxides (C=C- O −) or as α-ketocarbanions (− C-C= O). Thus, enolate ions can react with electrophiles either on oxygen or on carbon.
Mössbauer observed resonance in nuclei of solid iridium, which raised the question of why gamma-ray resonance was possible in solids but not in gases. Mössbauer proposed that, for the case of atoms bound into a solid, a fraction of the nuclear events could occur essentially without recoil under certain circumstances.
Resonance occurs when, at certain driving frequencies, the steady-state amplitude of x(t) is large compared to its amplitude at other driving frequencies. For the mass on a spring, resonance corresponds physically to the mass's oscillations having large displacements from the spring's equilibrium position at certain driving frequencies.
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Thus resonance is achievable not only about the possible energy-levels of a two-level atom, but also about the sub-levels in the energy created by lifting the degeneracy of the level. If the applied magnetic field is tuned properly, the polarization of resonance fluorescence can be used to describe the composition of the excited state.
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