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Dimethyl sulfide (DMS) or methylthiomethane is an organosulfur compound with the formula (CH 3) 2 S. It is the simplest thioether and has a characteristic disagreeable odor. It is a flammable liquid that boils at 37 °C (99 °F).
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It is an adduct between borane molecule (BH 3) and dimethyl sulfide molecule (S(CH 3) 2). It is a complexed borane reagent that is used for hydroborations and reductions . The advantages of BMS over other borane reagents, such as borane-tetrahydrofuran , are its increased stability and higher solubility. [ 1 ]
Dimethyl sulfite is prepared from a 1:2 ratio of thionyl chloride and methanol. [4] The reaction can be catalyzed by tertiary amine bases and likely proceeds via the chlorosulfinate (MeOS(O)Cl), [5] this intermediate will exist only fleetingly in the presence of methanol and as such its decomposition to methyl chloride and sulfur dioxide (via the slower SNi mechanism) is not observed to any ...
Dimethylsulfoniopropionate (DMSP), is an organosulfur compound with the formula (CH 3) 2 S + CH 2 CH 2 COO −.This zwitterionic metabolite can be found in marine phytoplankton, seaweeds, and some species of terrestrial and aquatic vascular plants.