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A single-displacement reaction, also known as single replacement reaction or exchange reaction, is an archaic concept in chemistry. It describes the stoichiometry of some chemical reactions in which one element or ligand is replaced by atom or group. [1] [2] [3] It can be represented generically as: + +
Substitution reactions in organic chemistry are classified either as electrophilic or nucleophilic depending upon the reagent involved, whether a reactive intermediate involved in the reaction is a carbocation, a carbanion or a free radical, and whether the substrate is aliphatic or aromatic. Detailed understanding of a reaction type helps to ...
Although this is a reaction solely of the dissociated ions in solution, it is sometimes referred to as a double displacement reaction: [1] Pb(NO 3) 2 + 2 KI → 2 KNO 3 + PbI 2. At higher temperature, this substance easily re-dissolves by dissociation to its colorless ions. The actual change (net ionic equation) is thus:
Even with this proviso, the electrode potentials of lithium and sodium – and hence their positions in the electrochemical series – appear anomalous. The order of reactivity, as shown by the vigour of the reaction with water or the speed at which the metal surface tarnishes in air, appears to be Cs > K > Na > Li > alkaline earth metals,
Reactions that proceed in the backward direction to approach equilibrium are often called non-spontaneous reactions, that is, is positive, which means that if they occur at constant temperature and pressure, they increase the Gibbs free energy of the reaction. They require input of energy to proceed in the forward direction.
Chemical reaction#Reaction types To a section : This is a redirect from a topic that does not have its own page to a section of a page on the subject. For redirects to embedded anchors on a page, use {{ R to anchor }} instead .
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