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The permeation of a material can be measured through numerous methods that quantify the permeability of a substance through a specific material. Permeability due to diffusion is measured in SI units of mol/(m･s･Pa) although Barrers are also commonly used.
A practical unit for permeability is the darcy (d), or more commonly the millidarcy (md) (1 d ≈ 10 −12 m 2). The name honors the French Engineer Henry Darcy who first described the flow of water through sand filters for potable water supply. Permeability values for most materials commonly range typically from a fraction to several thousand ...
Permeability is affected by the penetrant size. Larger gas molecules have a lower diffusion coefficient. The polymer chain flexibility and free volume in the polymer of the membrane material influence the diffusion coefficient, as the space within the permeable membrane must be large enough for the gas molecules to diffuse across.
In chemistry and materials science, diffusion also refers to the movement of fluid molecules in porous solids. [6] Different types of diffusion are distinguished in porous solids. Molecular diffusion occurs when the collision with another molecule is more likely than the collision with the pore walls. Under such conditions, the diffusivity is ...
P is the permeability, an experimentally determined membrane "conductance" for a given gas at a given temperature, c 2 − c 1 is the difference in concentration of the gas across the membrane for the direction of flow (from c 1 to c 2). Fick's first law is also important in radiation transfer equations.
Knudsen diffusion, named after Martin Knudsen, is a means of diffusion that occurs when the scale length of a system is comparable to or smaller than the mean free path of the particles involved. An example of this is in a long pore with a narrow diameter (2–50 nm) because molecules frequently collide with the pore wall. [ 1 ]
The building materials industry also manages the moisture barrier properties in architectural components to ensure the correct moisture levels in the internal spaces of buildings. Optoelectronic devices based on organic material, generally named OLEDs , need an encapsulation with low values of WVTR to guarantee the same performances over the ...
Oxygen permeability (OP) is a parameter of a contact lens that expresses the ability of the lens to let oxygen reach the eye by diffusion. In soft contact lenses, it is dependent on the thickness of the lens and the material of the lens, especially concerning the water content.