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Ammonium nitrate is a chemical compound with the formula NH4NO3. It is a white crystalline salt consisting of ions of ammonium and nitrate. It is highly soluble in water and hygroscopic as a solid, although it does not form hydrates. It is predominantly used in agriculture as a high-nitrogen fertilizer.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
The table below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure. Units of solubility are given in grams of substance per 100 millilitres of water (g/ (100 mL)), unless shown otherwise. The substances are listed in alphabetical order.
A number of other descriptive terms are also used to qualify the extent of solubility for a given application. For example, U.S. Pharmacopoeia gives the following terms, according to the mass m sv of solvent required to dissolve one unit of mass m su of solute: [8] (The solubilities of the examples are approximate, for water at 20–25 °C.)
The enthalpy of solution is most often expressed in kJ / mol at constant temperature. The energy change can be regarded as being made up of three parts: the endothermic breaking of bonds within the solute and within the solvent, and the formation of attractions between the solute and the solvent. An ideal solution has a null enthalpy of mixing.
Boiling-point elevation. Boiling-point elevation is the phenomenon whereby the boiling point of a liquid (a solvent) will be higher when another compound is added, meaning that a solution has a higher boiling point than a pure solvent. This happens whenever a non-volatile solute, such as a salt, is added to a pure solvent, such as water.
The term "calcium ammonium nitrate" is applied to multiple different, but closely related formulations. One variety of calcium ammonium nitrate is made by adding powdered limestone to ammonium nitrate; [1] [2] another, fully water-soluble version, is a mixture of calcium nitrate and ammonium nitrate, which crystallizes as a hydrated double salt: [3] 5Ca(NO 3) 2 •NH 4 NO 3 •10H 2 O.
The chemistry of ANFO detonation is the reaction of ammonium nitrate with a long-chain alkane (C n H 2n+2) to form nitrogen, carbon dioxide, and water.In an ideal stoichiometrically balanced reaction, ANFO is composed of about 94.5% AN and 5.5% FO by weight.