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The Solvay Process as an example of a cyclic process in chemical industry (green = reactants, black = intermediates, red = products) The Solvay process results in soda ash (predominantly sodium carbonate (Na 2 CO 3)) from brine (as a source of sodium chloride (NaCl)) and from limestone (as a source of calcium carbonate (CaCO 3)). [8] The ...
In chemistry, a reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs. [1]A chemical mechanism is a theoretical conjecture that tries to describe in detail what takes place at each stage of an overall chemical reaction.
The law states that the total enthalpy change during the complete course of a chemical reaction is independent of the sequence of steps taken. [ 2 ] [ 3 ] Hess's law is now understood as an expression of the fact that the enthalpy of a chemical process is independent of the path taken from the initial to the final state (i.e. enthalpy is a ...
Theoretical oxygen demand (ThOD) is the calculated amount of oxygen required to oxidize a compound to its final oxidation products. [1] However, there are some differences between standard methods that can influence the results obtained: for example, some calculations assume that nitrogen released from organic compounds is generated as ammonia, whereas others allow for ammonia oxidation to ...
A Markov process is called a reversible Markov process or reversible Markov chain if there exists a positive stationary distribution π that satisfies the detailed balance equations [13] =, where P ij is the Markov transition probability from state i to state j, i.e. P ij = P(X t = j | X t − 1 = i), and π i and π j are the equilibrium probabilities of being in states i and j, respectively ...
The magnitude of the equilibrium constant depends on the Gibbs free energy change for the reaction. [2] So, when the free energy change is large (more than about 30 kJ mol −1), the equilibrium constant is large (log K > 3) and the concentrations of the reactants at equilibrium are very small. Such a reaction is sometimes considered to be an ...
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A possible mechanism in two elementary steps that explains the rate equation is: NO 2 + NO 2 → NO + NO 3 (slow step, rate-determining) NO 3 + CO → NO 2 + CO 2 (fast step) In this mechanism the reactive intermediate species NO 3 is formed in the first step with rate r 1 and reacts with CO in the second step with rate r 2.
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