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The relative static permittivity of a solvent is a relative measure of its chemical polarity. For example, water is very polar, and has a relative static permittivity of 80.10 at 20 °C while n-hexane is non-polar, and has a relative static permittivity of 1.89 at 20 °C. [26]
In electromagnetism, the Clausius–Mossotti relation, named for O. F. Mossotti and Rudolf Clausius, expresses the dielectric constant (relative permittivity, ε r) of a material in terms of the atomic polarizability, α, of the material's constituent atoms and/or molecules, or a homogeneous mixture thereof.
Another common term encountered for both absolute and relative permittivity is the dielectric constant which has been deprecated in physics and engineering [2] as well as in chemistry. [ 3 ] By definition, a perfect vacuum has a relative permittivity of exactly 1 whereas at standard temperature and pressure , air has a relative permittivity of ...
Solvents with a dielectric constant (more accurately, relative static permittivity) greater than 15 (i.e. polar or polarizable) can be further divided into protic and aprotic. Protic solvents, such as water , solvate anions (negatively charged solutes) strongly via hydrogen bonding .
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However, the term fundamental physical constant has also been used occasionally to refer to certain universal dimensioned physical constants, such as the speed of light c, vacuum permittivity ε 0, Planck constant h, and the Newtonian constant of gravitation G, that appear in the most basic theories of physics.
The real (blue solid line) and imaginary (orange dashed line) components of relative permittivity are plotted for model with parameters = 3.2 eV, = 4.5 eV, = 100 eV, = 1 eV, and = 3.5. The Tauc–Lorentz model is a mathematical formula for the frequency dependence of the complex-valued relative permittivity , sometimes referred to as the ...
where R is the molar refractivity, is the Avogadro constant, is the electronic polarizability, p is the density of molecules, M is the molar mass, and = / is the material's relative permittivity or dielectric constant (or in optics, the square of the refractive index).