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Viscosity is a measure of a fluid's rate-dependent resistance to a change in shape or to movement of its neighboring portions relative to one another. [1] For liquids, it corresponds to the informal concept of thickness; for example, syrup has a higher viscosity than water. [2]
For kinematic viscosity, the SI unit is m^2/s. In engineering, the unit is usually Stoke or centiStoke, with 1 Stoke = 0.0001 m^2/s, and 1 centiStoke = 0.01 Stoke. For liquid, the dynamic viscosity is usually in the range of 0.001 to 1 Pascal-second, or 1 to 1000 centiPoise. The density is usually on the order of 1000 kg/m^3, i.e. that of water.
The poise (symbol P; / p ɔɪ z, p w ɑː z /) is the unit of dynamic viscosity (absolute viscosity) in the centimetre–gram–second system of units (CGS). [1] It is named after Jean Léonard Marie Poiseuille (see Hagen–Poiseuille equation). The centipoise (1 cP = 0.01 P) is more commonly used than the poise itself.
This functional relationship is described by a mathematical viscosity model called a constitutive equation which is usually far more complex than the defining equation of shear viscosity. One such complicating feature is the relation between the viscosity model for a pure fluid and the model for a fluid mixture which is called mixing rules.
A simple and widespread empirical correlation for liquid viscosity is a two-parameter exponential: = / This equation was first proposed in 1913, and is commonly known as the Andrade equation (named after British physicist Edward Andrade). It accurately describes many liquids over a range of temperatures.
In practice the unit has never been widely accepted and most international standards bodies do not include the poiseuille in their list of units. The third edition of the IUPAC Green Book , for example, lists Pa⋅s ( pascal - second ) as the SI-unit for dynamic viscosity, and does not mention the poiseuille.
Any equation that makes explicit one of these transport coefficient in the conservation variables is called an equation of state. [9] Apart from its dependence of pressure and temperature, the second viscosity coefficient also depends on the process, that is to say, the second viscosity coefficient is not just a material property.
Volume viscosity (also called bulk viscosity, or second viscosity or, dilatational viscosity) is a material property relevant for characterizing fluid flow. Common symbols are ζ , μ ′ , μ b , κ {\displaystyle \zeta ,\mu ',\mu _{\mathrm {b} },\kappa } or ξ {\displaystyle \xi } .