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Viscosity is a measure of a fluid's rate-dependent resistance to a change in shape or to movement of its neighboring portions relative to one another. [1] For liquids, it corresponds to the informal concept of thickness; for example, syrup has a higher viscosity than water. [2]
For kinematic viscosity, the SI unit is m^2/s. In engineering, the unit is usually Stoke or centiStoke, with 1 Stoke = 0.0001 m^2/s, and 1 centiStoke = 0.01 Stoke. For liquid, the dynamic viscosity is usually in the range of 0.001 to 1 Pascal-second, or 1 to 1000 centiPoise. The density is usually on the order of 1000 kg/m^3, i.e. that of water.
The poise (symbol P; / p ɔɪ z, p w ɑː z /) is the unit of dynamic viscosity (absolute viscosity) in the centimetre–gram–second system of units (CGS). [1] It is named after Jean Léonard Marie Poiseuille (see Hagen–Poiseuille equation). The centipoise (1 cP = 0.01 P) is more commonly used than the poise itself.
This functional relationship is described by a mathematical viscosity model called a constitutive equation which is usually far more complex than the defining equation of shear viscosity. One such complicating feature is the relation between the viscosity model for a pure fluid and the model for a fluid mixture which is called mixing rules.
A simple and widespread empirical correlation for liquid viscosity is a two-parameter exponential: = / This equation was first proposed in 1913, and is commonly known as the Andrade equation (named after British physicist Edward Andrade). It accurately describes many liquids over a range of temperatures.
Any equation that makes explicit one of these transport coefficient in the conservation variables is called an equation of state. [9] Apart from its dependence of pressure and temperature, the second viscosity coefficient also depends on the process, that is to say, the second viscosity coefficient is not just a material property.
The viscosity of the sample is then calculated using the following equation: = ˙ where is the sample viscosity, and is the force applied to the sample to pull it apart. Much like the Meissner-type rheometer, the SER rheometer uses a set of two rollers to strain a sample at a given rate. [ 31 ]
Volume viscosity (also called bulk viscosity, or second viscosity or, dilatational viscosity) is a material property relevant for characterizing fluid flow. Common symbols are ζ , μ ′ , μ b , κ {\displaystyle \zeta ,\mu ',\mu _{\mathrm {b} },\kappa } or ξ {\displaystyle \xi } .