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An antiknock agent is a gasoline additive used to reduce engine knocking and increase the fuel's octane rating by raising the temperature and pressure at which auto-ignition occurs.
In the U.S. MTBE has been used in gasoline at low levels since 1979, replacing tetraethyllead (TEL) as an antiknock (octane rating) additive to prevent engine knocking. [16] Oxygenates also help gasoline burn more completely, reducing tailpipe emissions. Oxygenates also dilute or displace gasoline components such as aromatics (e.g., benzene ...
Early research into "engine knocking" (also called "pinging" or "pinking") was also led by A.H. Gibson and Harry Ricardo in England and Thomas Boyd in the United States. The discovery that lead additives modified this behavior led to the widespread adoption of their use in the 1920s, and therefore more powerful, higher-compression engines. [16]
Fuel additives in general Ether and other flammable hydrocarbons have been used extensively as starting fluid for many difficult-to-start engines, especially diesel engines; Nitromethane, or "nitro", is a high-performance racing fuel; Acetone is a vaporization additive, mainly used with methanol racing fuel
In 1977, the US Congress amended the CAA to require advance approval by the EPA for the continued use of fuel additives such as MMT, ethanol, ethyl tert-butyl ether , etc. [9] The new CAA amendment required a "waiver" to allow use of fuel additives made of any elements other than carbon, hydrogen, oxygen (within certain limits) and nitrogen. [10]
The octane rating of gasoline is measured in a test engine and is defined by comparison with the mixture of 2,2,4-trimethylpentane (iso-octane) and normal heptane that would have the same anti-knocking capability as the fuel under test. The percentage, by volume, of 2,2,4-trimethylpentane in that mixture is the octane number of the fuel.
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