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The solubility of gas obeys Henry's law, that is, the amount of a dissolved gas in a liquid is proportional to its partial pressure. Therefore, placing a solution under reduced pressure makes the dissolved gas less soluble. Sonication and stirring under reduced pressure can usually enhance the efficiency.
Water is the medium of the oceans, the medium which carries all the substances and elements involved in the marine biogeochemical cycles. Water as found in nature almost always includes dissolved substances, so water has been described as the "universal solvent" for its ability to dissolve so many substances.
[27] [28] [29] Dissolved gas solubility is greater in cold water allowing for increased gas concentrations. [29] The Southern Ocean alone has been shown to be the most important high-latitude region controlling pre-industrial atmospheric carbon dioxide by general circulation model simulations. Circulation of water into the Antarctic deep-water ...
Colored dissolved organic matter (CDOM) is estimated to range from 20-70% of the carbon content of the oceans, being higher near river outlets and lower in the open ocean. [5] DOM can be recycled and put back into the food web through a process called microbial loop which is essential for nutrient cycling and supporting primary productivity. [ 6 ]
Measurements of primary productivity in the ocean can be made using this ratio. The concentration of oxygen dissolved in seawater varies according to biological processes (photosynthesis and respiration) as well as physical processes (air-sea gas exchange, temperature and pressure changes, lateral mixing and vertical diffusion).
In the ocean by volume, the most abundant gases dissolved in seawater are carbon dioxide (including bicarbonate and carbonate ions, 14 mL/L on average), nitrogen (9 mL/L), and oxygen (5 mL/L) at equilibrium at 24 °C (75 °F) [122] [123] [124] All gases are more soluble – more easily dissolved – in colder water than in warmer water. For ...
However, unlike many other gases (oxygen for instance), it reacts with water and forms a balance of several ionic and non-ionic species (collectively known as dissolved inorganic carbon, or DIC). These are dissolved free carbon dioxide (CO 2 (aq)), carbonic acid (H 2 CO 3), bicarbonate (HCO 3 −) and carbonate (CO 3 2−), and they interact ...
However, for aqueous solutions, the Henry's law solubility constant for many species goes through a minimum. For most permanent gases, the minimum is below 120 °C. Often, the smaller the gas molecule (and the lower the gas solubility in water), the lower the temperature of the maximum of the Henry's law constant.