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Pourbaix diagram of iron. [1] The Y axis corresponds to voltage potential. In electrochemistry, and more generally in solution chemistry, a Pourbaix diagram, also known as a potential/pH diagram, E H –pH diagram or a pE/pH diagram, is a plot of possible thermodynamically stable phases (i.e., at chemical equilibrium) of an aqueous electrochemical system.
While lists of noble metals can differ, they tend to cluster around gold and the six platinum group metals: ruthenium, rhodium, palladium, osmium, iridium, and platinum. In addition to this term's function as a compound noun , there are circumstances where noble is used as an adjective for the noun metal .
Marcel Pourbaix (16 September 1904 – 28 September 1998) was a Belgian chemist and pianist. [citation needed] He performed his most well known research at the University of Brussels, studying corrosion. [1] His biggest achievement is the derivation of potential-pH, better known as “Pourbaix Diagrams”.
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According to the Pourbaix diagram for iron, the metal is passive when the pH is above 9.5. [1] The carbon dioxide in the air reacts with the alkali in the cement and makes the pore water more acidic, thus lowering the pH. Carbon dioxide will start to carbonatate the cement in the concrete from the moment the object is made.
Similar to Pourbaix diagrams for the speciation of redox species as a function of the redox potential and the pH, ionic partition diagrams indicate in which phase an acid or a base is predominantly present in a biphasic system as a function of the Galvani potential difference between the two phases and the pH of the aqueous solution.