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The classic example of a dehydration reaction is the Fischer esterification, which involves treating a carboxylic acid with an alcohol to give an ester RCO 2 H + R′OH ⇌ RCO 2 R′ + H 2 O. Often such reactions require the presence of a dehydrating agent, i.e. a substance that reacts with water.
The Birch reduction is an organic reaction that is used to convert arenes to 1,4-cyclohexadienes.The reaction is named after the Australian chemist Arthur Birch and involves the organic reduction of aromatic rings in an amine solvent (traditionally liquid ammonia) with an alkali metal (traditionally sodium) and a proton source (traditionally an alcohol).
Magnesium bicarbonate or magnesium hydrogencarbonate, Mg(H CO 3) 2, is the bicarbonate salt of magnesium. It can be formed through the reaction of dilute solutions of carbonic acid (such as seltzer water) and magnesium hydroxide (milk of magnesia). It can be prepared through the synthesis of magnesium acetate and sodium bicarbonate:
The word hydrolysis is applied to chemical reactions in which a substance reacts with water. In organic chemistry, the products of the reaction are usually molecular, being formed by combination with H and OH groups (e.g., hydrolysis of an ester to an alcohol and a carboxylic acid). In inorganic chemistry, the word most often applies to cations ...
Magnesium perchlorate is a white powder that is easily soluble in water, which can be obtained by the reaction of magnesium oxide and perchloric acid. The hexahydrate crystallizes from the solution, and then it is dried with phosphorus pentoxide in a vacuum at 200~250 °C to obtain the anhydrous form.
Although the reagents still need to be dry, ultrasound can allow Grignard reagents to form in wet solvents by activating the magnesium such that it consumes the water. [2] As is common for reactions involving solids and solution, the formation of Grignard reagents is often subject to an induction period. During this stage, the passivating oxide ...
However, trapping with water, to form the acid is the most common form. General homologation reaction, Arndt-Eistert has R 2 = H, RXH=H 2 O. In the most basic form, where R 2 = H, RXH=H 2 O, the reaction lengthens the alkyl chain of a carboxylic acid by a methylene. However, there is great synthetic utility in the variety of reactions one can ...
Acrolein and malonic acid react in pyridine to give trans-2,4-pentadienoic acid with the loss of carbon dioxide. The Doebner modification of the Knoevenagel condensation entails the use of pyridine as a solvent with at least one of the withdrawing groups on the nucleophile is a carboxylic acid , for example, with malonic acid .