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Table data (above) obtained from CRC Handbook of Chemistry and Physics 44th ed. The (s) notation indicates equilibrium temperature of vapor over solid. Otherwise temperature is equilibrium of vapor over liquid. log 10 of anydrous ammonia vapor pressure. Uses formula shown below.
Azanide is the IUPAC-sanctioned name for the anion NH − 2.The term is obscure; derivatives of NH − 2 are almost invariably referred to as amides, [1] [2] [3] despite the fact that amide also refers to the organic functional group – C(=O)−NR 2.
In aqueous solution, ammonia deprotonates a small fraction of the water to give ammonium and hydroxide according to the following equilibrium: . NH 3 + H 2 O ⇌ NH + 4 + OH −.. In a 1 M ammonia solution, about 0.42% of the ammonia is converted to ammonium, equivalent to pH = 11.63 because [NH +
Acetonitrile is less basic than DMSO, and, so, in general, acids are weaker and bases are stronger in this solvent. Some pK a values at 25 °C for acetonitrile (ACN) [37] [38] [39] and dimethyl sulfoxide (DMSO). [40] are shown in the following tables. Values for water are included for comparison.
Of these, 39 were tabulated in extensive tables of the chemistry among C, N and O compounds. [182] A review of interstellar ammonia cites the following reactions as the principal dissociation mechanisms: [174]
Ammonium is a modified form of ammonia that has an extra hydrogen atom. It is a positively charged molecular ion with the chemical formula NH + 4 or [NH 4] +.It is formed by the addition of a proton (a hydrogen nucleus) to ammonia (NH 3).
In chemistry, the amino radical, ·NH 2, also known as the aminyl or azanyl, is the neutral form of the amide ion (NH − 2). Aminyl radicals are highly reactive and consequently short-lived, like most radicals; however, they form an important part of nitrogen chemistry. In sufficiently high concentration, amino radicals dimerise to form hydrazine
Dimethylamine is a weak base and the pKa of the ammonium CH 3-NH + 2 -CH 3 is 10.73, a value above methylamine (10.64) and trimethylamine (9.79). Dimethylamine reacts with acids to form salts, such as dimethylamine hydrochloride, an odorless white solid with a melting point of 171.5 °C.