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The single-bonded oxygen atoms that are not shared are completed with acidic hydrogen atoms. The general formula of a phosphoric acid is H n+2−2x P n O 3n+1−x, where n is the number of phosphorus atoms and x is the number of fundamental cycles in the molecule's structure, between 0 and n + 2 / 2 . Pyrophosphate anion. Trimethyl ...
It is a diprotic acid, the hydrogenphosphite ion, HP(O) 2 (OH) − is a weak acid: HP(O) 2 (OH) − → HPO 2− 3 + H + pK a = 6.7. The conjugate base HP(O) 2 (OH) − is called hydrogen phosphite, and the second conjugate base, HPO 2− 3, is the phosphite ion. [8] (Note that the IUPAC recommendations are hydrogen phosphonate and phosphonate ...
The molecule displays P(═O)H to P–OH tautomerism similar to that of phosphorous acid; the P(═O) form is strongly favoured. [6] HPA is usually supplied as a 50% aqueous solution and heating at low temperatures (up to about 90 °C) prompts it to react with water to form phosphorous acid and hydrogen gas. H 3 PO 2 + H 2 O → H 3 PO 3 + H 2
4 RR′R″ where one or more hydrogen atoms are replaced by organic groups. An example is trimethyl phosphate, (CH 3) 3 PO 4. The term also refers to the trivalent functional group OP(O-) 3 in such esters. Phosphates may contain sulfur in place of one or more oxygen atoms (thiophosphates and organothiophosphates).
The hydrogen fluoride (HF) gas is streamed into a wet (water) scrubber producing hydrofluoric acid. In both cases the phosphoric acid solution usually contains 23–33% P 2 O 5 (32–46% H 3 PO 4). It may be concentrated to produce commercial-or merchant-grade phosphoric acid, which contains about 54–62% P 2 O 5 (75–85% H 3 PO 4).
The single-bonded oxygen atoms that are not shared are completed with acidic hydrogen atoms. Their generic formula is H n − x +2 P n O 3 n − x +1 , where n is the number of phosphorus atoms and x is the number of fundamental cycles in the molecule's structure.
Most hydrogenphosphate salts are colorless, water soluble, and nontoxic. It is a conjugate acid of phosphate [PO 4] 3-and a conjugate base of dihydrogen phosphate [H 2 PO 4] −. It is formed when a pyrophosphate anion [P 2 O 7] 4− reacts with water H 2 O by hydrolysis, which can give hydrogenphosphate: [P 2 O 7] 4− + H 2 O ⇌ 2 [HPO 4] 2−
These compounds contain a layer polymeric anion consisting of HPO 3 tetrahedra linked by hydrogen bonds. These layers are interleaved by layers of metal cations. [8] Organic esters of hydrogen phosphites are anions with the formula HP(O) 2 OR − (R = organic group). One commercial example is the fungicide fosetyl-Al with the formula [C 2 H 5 ...