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ch 3 ch 2 ch 2 oh + o 2 + nh 3 → ch 3 ch 2 c≡n + 3 h 2 o Propionitrile is a byproduct of the electrodimerisation of acrylonitrile to adiponitrile . In the laboratory propanenitrile can also be produced by the dehydration of propionamide , by catalytic reduction of acrylonitrile , or by distilling ethyl sulfate and potassium cyanide .
C 3 H 2 O: Molar mass: 54.048 g·mol −1 Appearance colorless liquid Density: ... Its acetal can be prepared from acrolein. [2] Occurrence in interstellar medium
The active hydrogen component has the forms: [3] Z−CH 2 −Z or Z−CHR−Z for instance diethyl malonate, Meldrum's acid, ethyl acetoacetate or malonic acid, or cyanoacetic acid. [1] Z−CHRR', for instance nitromethane. where Z is an electron withdrawing group. Z must be powerful enough to facilitate deprotonation to the enolate ion even ...
Propionaldehyde exhibits the reactions characteristic of alkyl aldehydes, e.g. hydrogenation, aldol condensations, oxidations, etc. It is the simplest aldehyde with a prochiral methylene such that α-functionalized derivatives (CH 3 CH(X)CHO) are chiral. If water is available, propionaldehyde exists in equilibrium with 1,1-propanediol, a ...
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
2,2-Dimethoxypropane (DMP) is an organic compound with the formula (CH 3) 2 C(OCH 3) 2. A colorless liquid, it is the product of the condensation of acetone and methanol. DMP is used as a water scavenger in water-sensitive reactions. Upon acid-catalyzed reaction, DMP reacts quantitatively with water to form acetone and methanol. [2]
[3] Reaction of the sodium cyanoacetate with ethyl bromide in an aqueous–organic two-phase system in the presence of a phase transfer catalyst. [4] Oxidation of 3-ethoxypropionitrile, an ether, with oxygen under pressure in the presence of cobalt(II) acetate tetrahydrate as catalyst and N-hydroxyphthalimide as a radical generator. [5]
The product, CH 3 CH(OCH 2 CH 3) 2, is formally named 1,1-diethoxyethane but is commonly referred to as "acetal". [39] This can cause confusion as "acetal" is more commonly used to describe compounds with the functional groups RCH(OR') 2 or RR'C(OR'') 2 rather than referring to this specific compound — in fact, 1,1-diethoxyethane is also ...