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A fraction in chemistry is a quantity collected from a batch of a substance in a fractionating separation process. In such a process, a mixture is separated into fractions, which have compositions that vary according to a gradient. A fraction can be defined as a group of chemicals that have similar boiling points.
UNIQUAC requires two basic underlying parameters: relative surface and volume fractions are chemical constants, which must be known for all chemicals (q i and r i parameters, respectively). Empirical parameters between components that describes the intermolecular behaviour.
When comparing a polar and nonpolar molecule with similar molar masses, the polar molecule in general has a higher boiling point, because the dipole–dipole interaction between polar molecules results in stronger intermolecular attractions. One common form of polar interaction is the hydrogen bond, which is also
The nearer two molecules are in this three-dimensional space, the more likely they are to dissolve into each other. To determine if the parameters of two molecules (usually a solvent and a polymer) are within range, a value called interaction radius is given to the substance being dissolved. This value determines the radius of the sphere in ...
Because the individual masses of the ingredients of a mixture sum to , their mass fractions sum to unity: ∑ i = 1 n w i = 1. {\displaystyle \sum _{i=1}^{n}w_{i}=1.} Mass fraction can also be expressed, with a denominator of 100, as percentage by mass (in commercial contexts often called percentage by weight , abbreviated wt.% or % w/w ; see ...
Examples of hydrophobic molecules include the alkanes, oils, fats, and greasy substances in general. Hydrophobic materials are used for oil removal from water, the management of oil spills, and chemical separation processes to remove non-polar substances from polar compounds. [2] Hydrophobic is often used interchangeably with lipophilic, "fat ...
In general, the partial molar volume of a substance X in a mixture is the change in volume per mole of X added to the mixture. The partial molar volumes of the components of a mixture vary with the composition of the mixture, because the environment of the molecules in the mixture changes with the composition.
The mathematics is so complicated for polar and non-spherical molecules that it is very difficult to get practical models for viscosity. The purely theoretical approach will therefore be left out for the rest of this article, except for some visits related to dilute gas and significant structure theory.
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