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Total fatty matter (TFM) is one of the most important characteristics describing the quality of soap and is always specified in commercial transactions. It is defined as the total amount of fatty matter, mostly fatty acids, that can be separated from a sample after splitting with a mineral acid, usually hydrochloric acid.
Hexanoic acid CH 3 (CH 2) 4 COOH C6:0 Enanthic acid: Heptanoic acid CH 3 (CH 2) 5 COOH C7:0 Caprylic acid: Octanoic acid CH 3 (CH 2) 6 COOH C8:0 Pelargonic acid: Nonanoic acid CH 3 (CH 2) 7 COOH C9:0 Capric acid: Decanoic acid CH 3 (CH 2) 8 COOH C10:0 Undecylic acid: Undecanoic acid CH 3 (CH 2) 9 COOH C11:0 Lauric acid: Dodecanoic acid CH 3 (CH ...
Fatty acids are mainly used in the production of soap, both for cosmetic purposes and, in the case of metallic soaps, as lubricants. Fatty acids are also converted, via their methyl esters, to fatty alcohols and fatty amines, which are precursors to surfactants, detergents, and lubricants. [17]
German hard soap French hard soap (Marseille) Layered, packaged French hard soap Box of Austrian hard soap (circa 1914) Hard soaps (Latin: sapo medicatus), also termed soda soaps in older terminology, are categorized under soaps and are typically sodium salts of fatty acids. They vary in color from white to brownish and have a fatty acid ...
The reaction of fatty acids with base is the other main method of saponification. In this case, the reaction involves neutralization of the carboxylic acid . The neutralization method is used to produce industrial soaps such as those derived from magnesium, the transition metals, and aluminium.
[1] [2] [3] It is a measure of the average molecular weight (or chain length) of all the fatty acids present in the sample in form of triglycerides. The higher the saponification value, the lower the fatty acids average length, the lighter the mean molecular weight of triglycerides and vice versa.
In this context, soap is used in its formal sense, a metal salt of a fatty acid: in this case stearic acid. It is a white solid that repels water. It is a white solid that repels water. It is insoluble in polar solvents such as alcohol and ether but soluble in aromatic hydrocarbons (e.g., benzene ) and chlorinated hydrocarbons when heated.
The major product of this industry is soap, approximately 8.9×10 6 tons of which were produced in 1990. Other major oleochemicals include fatty acids, fatty acid methyl esters, fatty alcohols and fatty amines. Glycerol is a side product of all of these processes. [1]