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The method was simple and efficient to prepare the material in gram amounts per day (1990) which has boosted the fullerene research and is even today applied for the commercial production of fullerenes. The discovery of practical routes to C 60 led to the exploration of a new field of chemistry involving the study of fullerenes.
Scheme 1 presents an overview of the first step, the creation of a 13 membered ring orifice on the fullerene surface. A 1,2,4-triazine 2 is fitted with two phenyl groups and a pyridine group for reasons of solubility and reacted in 1,2-dichlorobenzene with pristine C 60 fullerene 2 in a Diels-Alder reaction at high temperature and for an extended reaction time.
The calculated data allows using C 60 fullerene as a Faraday cage, [13] which isolates the encapsulated atom from the external electric field. The mentioned relations should be typical for the more complicated endohedral structures (e.g., C 60 @C 240 [14] and giant fullerene-containing "onions" [15]).
According to the IUPAC, to name a fullerene, one must cite the number of member atoms for the rings which comprise the fullerene, its symmetry point group in the Schoenflies notation, and the total number of atoms. For example, buckminsterfullerene C 60 is systematically named (C 60-I h)[5,6]fullerene. The name of the point group should be ...
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