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In inorganic chemistry, bicarbonate (IUPAC-recommended nomenclature: hydrogencarbonate [2]) is an intermediate form in the deprotonation of carbonic acid. It is a polyatomic anion with the chemical formula H C O − 3. Bicarbonate serves a crucial biochemical role in the physiological pH buffering system. [3]
Sodium bicarbonate can sometimes be used as a mild neutralization agent and a safer alternative to strong bases like sodium hydroxide. [79] Reaction of sodium bicarbonate and an acid produces a salt and carbonic acid, which readily decomposes to carbon dioxide and water: [79] NaHCO 3 + HCl → NaCl + H 2 O+CO 2 H 2 CO 3 → H 2 O + CO 2 (g)
Carbonic acid monomers exhibit three conformational isomers: cis–cis, cis–trans, and trans–trans. [10] At low temperatures and atmospheric pressure, solid carbonic acid is amorphous and lacks Bragg peaks in X-ray diffraction. [11] But at high pressure, carbonic acid crystallizes, and modern analytical spectroscopy can measure its geometry.
Most of the carbonic acid then dissociates to bicarbonate and hydrogen ions. The bicarbonate buffer system is an acid-base homeostatic mechanism involving the balance of carbonic acid (H 2 CO 3), bicarbonate ion (HCO − 3), and carbon dioxide (CO 2) in order to maintain pH in the blood and duodenum, among other tissues, to support proper ...
Aqueous carbon dioxide reacts with water to form carbonic acid which is very unstable and will dissociate rapidly into hydronium and bicarbonate. Therefore, in seawater, dissolved inorganic carbon is commonly referred to as the collection of bicarbonate, carbonate ions, and dissolved carbon dioxide (CO 2, H 2 CO 3, HCO − 3, CO 2− 3).
The inorganic carbon species include carbon dioxide, carbonic acid, bicarbonate anion, and carbonate. [5] It is customary to express carbon dioxide and carbonic acid simultaneously as CO 2 *. C T is a key parameter when making measurements related to the pH of natural aqueous systems, [6] and carbon dioxide flux estimates.
Hydrogen ions are formed from the dissociation of carbonic acid. Water is a very minor source of hydrogen ions in comparison to carbonic acid. Carbonic acid is formed from carbon dioxide and water by carbonic anhydrase. The bicarbonate ion (HCO 3 −) is exchanged for a chloride ion (Cl −) on the basal side of the cell and the bicarbonate ...
This compound is a source of carbon dioxide for leavening in baking. It can substitute for baking soda (sodium bicarbonate) for those with a low-sodium diet, [4] and it is an ingredient in low-sodium baking powders. [5] [6] As an inexpensive, nontoxic base, it is widely used in diverse application to regulate pH or as a reagent.