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While most metals form arsenides, only the alkali and alkaline earth metals form mostly ionic arsenides. The structure of Na 3 As is complex with unusually short Na–Na distances of 328–330 pm which are shorter than in sodium metal, and this indicates that even with these electropositive metals the bonding cannot be straightforwardly ionic. [10]
In chemistry, an arsenide is a compound of arsenic with a less electronegative element or elements. Many metals form binary compounds containing arsenic, and these are called arsenides. They exist with many stoichiometries, and in this respect arsenides are similar to phosphides. [1]
The chemistry of ununennium is predicted to be similar to that of the alkali metals, [1] but it would probably behave more like potassium [90] or rubidium [1] than caesium or francium. This is due to relativistic effects, as in their absence periodic trends would predict ununennium to be even more reactive than caesium and francium.
Sodium metal is highly reducing, with the standard reduction potential for the Na + /Na couple being −2.71 volts, [3] though potassium and lithium have even more negative potentials. [4] The thermal, fluidic, chemical, and nuclear properties of molten sodium metal have caused it to be one of the main coolants of choice for the fast breeder ...
Cs > K > Na > Li > alkaline earth metals, i.e., alkali metals > alkaline earth metals, the same as the reverse order of the (gas-phase) ionization energies. This is borne out by the extraction of metallic lithium by the electrolysis of a eutectic mixture of lithium chloride and potassium chloride: lithium metal is formed at the cathode, not ...
An alkalide is a chemical compound in which alkali metal atoms are anions (negative ions) with a charge or oxidation state of −1. Until the first discovery of alkalides in the 1970s, [1] [2] [3] alkali metals were known to appear in salts only as cations (positive ions) with a charge or oxidation state of +1. [4]
The alkaline earth metals are six chemical elements in group 2 of the periodic table. They are beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), and radium (Ra). [ 1 ] The elements have very similar properties: they are all shiny, silvery-white, somewhat reactive metals at standard temperature and pressure .
The alkaline earth metals (Be, Mg, Ca, Sr, Ba, and Ra) are the second most reactive metals in the periodic table, and, like the Group 1 metals, have increasing reactivity with increasing numbers of energy levels. Beryllium (Be) is the only alkaline earth metal that does not react with water or steam, even if the metal is heated red hot. [9]