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The IUPAC definition [1] of relative atomic mass is: An atomic weight (relative atomic mass) of an element from a specified source is the ratio of the average mass per atom of the element to 1/12 of the mass of an atom of 12 C. The definition deliberately specifies "An atomic weight ...", as an element will have different relative atomic masses ...
The atomic mass (relative isotopic mass) is defined as the mass of a single atom, which can only be one isotope (nuclide) at a time, and is not an abundance-weighted average, as in the case of relative atomic mass/atomic weight. The atomic mass or relative isotopic mass of each isotope and nuclide of a chemical element is, therefore, a number ...
The mass number should also not be confused with the standard atomic weight (also called atomic weight) of an element, which is the ratio of the average atomic mass of the different isotopes of that element (weighted by abundance) to the atomic mass constant. [9] The atomic weight is a mass ratio, while the mass number is a counted number (and ...
However, the relative atomic mass of each isotope is quite close to its mass number (always within 1%). The only isotope whose atomic mass is exactly a natural number is 12 C, which has a mass of 12 Da; because the dalton is defined as 1/12 of the mass of a free neutral carbon-12 atom in the ground state.
Atomic weight and relative atomic mass are synonyms. The standard atomic weight is a special value of the relative atomic mass. It is defined as the "recommended values" of relative atomic masses of sources in the local environment of the Earth's crust and atmosphere as determined by the IUPAC Commission on Atomic Weights and Isotopic ...
Each distinct atomic number therefore corresponds to a class of atom: these classes are called the chemical elements. [5] The chemical elements are what the periodic table classifies and organizes. Hydrogen is the element with atomic number 1; helium, atomic number 2; lithium, atomic number 3; and so on.
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The electron relative atomic mass also enters into the calculation of all other relative atomic masses. By convention, relative atomic masses are quoted for neutral atoms, but the actual measurements are made on positive ions, either in a mass spectrometer or a Penning trap. Hence the mass of the electrons must be added back on to the measured ...