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2,4-Dichlorophenoxyacetic acid is an organic compound with the chemical formula Cl 2 C 6 H 3 OCH 2 CO 2 H.It is usually referred to by its ISO common name 2,4-D. [4] It is a systemic herbicide that kills most broadleaf weeds by causing uncontrolled growth, but most grasses such as cereals, lawn turf, and grassland are relatively unaffected.
The low cost of 2,4-D has led to continued usage today, and it remains one of the most commonly used herbicides in the world. [16] Like other acid herbicides, current formulations use either an amine salt (often trimethylamine ) or one of many esters of the parent compound.
The first reaction is the formation of the N-2,4-dinitrophenyl-pyridinium salt (2). This salt is typically isolated and purified by recrystallization. The formation of the DNP-pyridinium salt. Upon heating a primary amine with the N-2,4-dinitrophenyl-pyridinium salt (2), the addition
Amine. In chemistry, amines (/ ə ˈ m iː n, ˈ æ m iː n /, [1] [2] UK also / ˈ eɪ m iː n / [3]) are compounds and functional groups that contain a basic nitrogen atom with a lone pair.Formally, amines are derivatives of ammonia (NH 3), wherein one or more hydrogen atoms have been replaced by a substituent such as an alkyl or aryl group [4] (these may respectively be called alkylamines ...
2-methyl-4-chlorophenol + ClCH 2 CO 2 H + base → MCPA + base·HCl (hydrochloric acid) By the end of 1941 it was clear to the Templeman group that MCPA was one of the most active compounds tested but other auxin herbicides including 2,4-D were also effective.
Dimethylamine is an organic compound with the formula (CH 3) 2 NH. This secondary amine is a colorless, flammable gas with an ammonia -like odor. Dimethylamine is commonly encountered commercially as a solution in water at concentrations up to around 40%.
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Today, only R-dichlorprop (also called dichlorprop-p or 2,4-DP-p) and its derivatives are sold as pesticides in the United States. Dichlorprop is a carboxylic acid, and like related herbicides with free acid groups, it is often sold as a salt or ester. Currently, the 2-ethylhexyl ester is used commercially. The butoxyethyl and isooctyl esters ...
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