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The discovery of isotopes of oxygen in 1929 required a more precise definition of the unit. Two distinct definitions came into use. Chemists choose to define the AMU as 1 / 16 of the average mass of an oxygen atom as found in nature; that is, the average of the masses of the known isotopes, weighted by their natural abundance.
The molar mass is defined as the mass of a given substance divided by the amount of the substance, and is expressed in grams per mol (g/mol). That makes the molar mass an average of many particles or molecules (potentially containing different isotopes), and the molecular mass the mass of one specific particle or molecule. The molar mass is ...
During that period, the molar mass of carbon-12 was thus exactly 12 g/mol, by definition. Since 2019, a mole of any substance has been redefined in the SI as the amount of that substance containing an exactly defined number of particles, 6.022 140 76 × 10 23. The molar mass of a compound in g/mol thus is equal to the mass of this number of ...
Historically, the mole was defined as the amount of substance in 12 grams of the carbon-12 isotope.As a consequence, the mass of one mole of a chemical compound, in grams, is numerically equal (for all practical purposes) to the mass of one molecule or formula unit of the compound, in daltons, and the molar mass of an isotope in grams per mole is approximately equal to the mass number ...
For convenience in avoiding conversions in the imperial (or US customary units), some engineers adopted the pound-mole (notation lb-mol or lbmol), which is defined as the number of entities in 12 lb of 12 C. One lb-mol is equal to 453.592 37 g‑mol, [6] which is the same numerical value as the number of grams in an international avoirdupois pound.
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By definition, the atomic mass of carbon-12 is 12 Da, giving a molar mass of 12 g/mol. The number of molecules per mole in a substance is given by the Avogadro constant, exactly 6.022 140 76 × 10 23 mol −1 since the 2019 revision of the SI. Thus, to calculate the stoichiometry by mass, the number of molecules required for each reactant is ...