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Isotope geochemistry is an aspect of geology based upon the study of natural variations in the relative abundances of isotopes of various elements. Variations in isotopic abundance are measured by isotope-ratio mass spectrometry , and can reveal information about the ages and origins of rock, air or water bodies, or processes of mixing between ...
Key principles of the Nd isotope system were laid out in his 1988 book, Neodymium Isotope Geochemistry: An Introduction. DePaolo's work has since led to significant advances in using various isotope systems to constrain rates of metamorphic processes [6], quantify continental weathering and elemental seawater budgets through geologic time and ...
Measurement of natural variations in the abundances of stable isotopes of the same element is normally referred to as stable isotope analysis. This field is of interest because the differences in mass between different isotopes leads to isotope fractionation, causing measurable effects on the isotopic composition of samples, characteristic of their biological or physical history.
Theoretically, such stable isotopes could include the radiogenic daughter products of radioactive decay, used in radiometric dating. However, the expression stable-isotope ratio is preferably used to refer to isotopes whose relative abundances are affected by isotope fractionation in nature. This field is termed stable isotope geochemistry.
Since its original descriptions, the Urey–Bigeleisen–Mayer equation has taken many forms. Given an isotopic exchange reaction + = +, such that designates a molecule containing an isotope of interest, the equation can be expressed by relating the equilibrium constant, , to the product of partition function ratios, namely the translational, rotational, vibrational, and sometimes electronic ...
Isotope fractionation occurs during a phase transition, when the ratio of light to heavy isotopes in the involved molecules changes.When water vapor condenses (an equilibrium fractionation), the heavier water isotopes (18 O and 2 H) become enriched in the liquid phase while the lighter isotopes (16 O and 1 H) tend toward the vapor phase.
The most widely studied and used isotopes in archaeology are carbon, oxygen, nitrogen, strontium and calcium. [2] An isotope is an atom of an element with an abnormal number of neutrons, changing their atomic mass. [2] Isotopes can be subdivided into stable and unstable or radioactive. Unstable isotopes decay at a predictable rate over time. [2]
D 0 is number of atoms of the daughter isotope in the original or initial composition, n is number of atoms of the parent isotope in the sample at the present, λ is the decay constant of the parent isotope, equal to the inverse of the radioactive half-life of the parent isotope [6] times the natural logarithm of 2, and
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