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In thermodynamics, the enthalpy of sublimation, or heat of sublimation, is the heat required to sublimate (change from solid to gas) one mole of a substance at a given combination of temperature and pressure, usually standard temperature and pressure (STP). It is equal to the cohesive energy of the solid.
A sublimatory [1] [2] or sublimation apparatus is equipment, commonly laboratory glassware, for purification of compounds by selective sublimation. In principle, the operation resembles purification by distillation , except that the products do not pass through a liquid phase .
The term was later also applied to the indirect sublimation transfer printing process, which uses a standard ink-jet printer to deposit sublimation-capable ink onto a transfer sheet. The printed transfer sheet is then pressed with the substrate with heat, transferring the dye to the substrate, such as plastic or fabric, via sublimation.
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Dye-sublimation printing is a direct-to-garment digital printing technology using full color artwork to transfer images to polyester and polymer-coated substrate based T-shirts. Dye-sublimation (also commonly referred to as all-over printing) came into widespread use in the 21st century, enabling some designs previously impossible.
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The sublimation that occurs at the solid-gas boundary (critical sublimation point) (corresponding to boiling in vaporization) may be called rapid sublimation, and the substance sublimes rapidly. The words "gradual" and "rapid" have acquired special meanings in this context and no longer describe the rate of sublimation. [citation needed]
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