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The bond valence method or mean method (or bond valence sum) (not to be mistaken for the valence bond theory in quantum chemistry) is a popular method in coordination chemistry to estimate the oxidation states of atoms. It is derived from the bond valence model, which is a simple yet robust model for validating chemical structures with ...
Tolerance stackups or tolerance stacks are used to describe the problem-solving process in mechanical engineering of calculating the effects of the accumulated variation that is allowed by specified dimensions and tolerances. Typically these dimensions and tolerances are specified on an engineering drawing.
It was originally only used to describe the perovskite ABO 3 structure, but now tolerance factors are also used for ilmenite. [2] Alternatively the tolerance factor can be used to calculate the compatibility of an ion with a crystal structure. [3] The first description of the tolerance factor for perovskite was made by Victor Moritz Goldschmidt ...
For example, if a shaft with a nominal diameter of 10 mm is to have a sliding fit within a hole, the shaft might be specified with a tolerance range from 9.964 to 10 mm (i.e., a zero fundamental deviation, but a lower deviation of 0.036 mm) and the hole might be specified with a tolerance range from 10.04 mm to 10.076 mm (0.04 mm fundamental ...
In coordination chemistry and crystallography, the geometry index or structural parameter (τ) is a number ranging from 0 to 1 that indicates what the geometry of the coordination center is. The first such parameter for 5-coordinate compounds was developed in 1984. [ 1 ]
In gas chromatography, the Kovats retention index (shorter Kovats index, retention index; plural retention indices) is used to convert retention times into system-independent constants. The index is named after the Hungarian-born Swiss chemist Ervin Kováts , who outlined the concept in the 1950s while performing research into the composition ...
Hansen solubility parameters were developed by Charles M. Hansen in his Ph.D thesis in 1967 [1] [2] as a way of predicting if one material will dissolve in another and form a solution. [3]
Pitting resistance equivalent number (PREN) is a predictive measurement of a stainless steel's resistance to localized pitting corrosion based on its chemical composition. In general: the higher PREN-value, the more resistant is the stainless steel to localized pitting corrosion by chloride.