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Ammonium fluoride is a critical component of buffered oxide etch (BOE), a wet etchant used in microfabrication. It acts as the buffering agent in a solution of concentrated HF , creating an etchant with a more controllable rate of etching (than that of simple concentrated HF solutions).
Tetra-n-butylammonium fluoride, commonly abbreviated to TBAF and n-Bu 4 NF, is a quaternary ammonium salt with the chemical formula (CH 3 CH 2 CH 2 CH 2) 4 N + F −. It is commercially available as the white solid trihydrate and as a solution in tetrahydrofuran. TBAF is used as a source of fluoride ion in organic solvents. [1]
This is a list of CAS numbers by chemical formulas and chemical compounds, ... aluminium fluoride: 7784–18–1 AlI 3: aluminium iodide: ... NH 4 NO 3: ammonium ...
Historically, there have been two main approaches to prepare tetramethylammonium fluoride: hydrofluoric acid neutralization of tetramethylammonium hydroxide, and salt metathesis between different ammonium salts and inorganic fluoride sources, such as KF or CsF. [1] Because the fluoride anion is extremely basic, the salt slowly reacts with ...
Tetrabutylammonium is a quaternary ammonium cation with the formula [N(C 4 H 9) 4] +, also denoted [NBu 4] + (where Bu = butyl group). It is used in the research laboratory to prepare lipophilic salts of inorganic anions. Relative to tetraethylammonium derivatives, tetrabutylammonium salts are more lipophilic but crystallize less readily.
Ammonium fluorosilicate (also known as ammonium hexafluorosilicate, ammonium fluosilicate or ammonium silicofluoride) has the formula (NH 4) 2 SiF 6. It is a toxic chemical, like all salts of fluorosilicic acid. [4] It is made of white crystals, [5] which have at least three polymorphs [6] and appears in nature as rare minerals cryptohalite or ...
Buffered oxide etch is commonly used for more controllable etching. [1] Buffering HF with NH 4 F results in a solution with a more stable pH; thus, more stable concentrations of HF and HF − 2, and a more stable etch rate. [2] Some oxides produce insoluble products in HF solutions.
Benzyltrimethylammonium fluoride is a quaternary ammonium salt. It is commercially available as the hydrate. The compound is a source of organic-soluble fluoride to removal of silyl ether protecting groups. As is the case for tetra-n-butylammonium fluoride and most other quaternary ammonium fluorides, the compound cannot be obtained in ...