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Iron(II) chloride tetrahydrate, FeCl 2 ·4H 2 O. In chemistry, iron(II) refers to the element iron in its +2 oxidation state. The adjective ferrous or the prefix ferro-is often used to specify such compounds, as in ferrous chloride for iron(II) chloride (FeCl 2). The adjective ferric is used instead for iron(III) salts, containing the cation Fe 3+.
Chemical formula. Fe(CN) 2 Molar mass: 107.881 ... Iron(II) cyanide is an inorganic compound with the empirical formula Fe(CN) 2. It may have a Fe 2 [Fe ...
An example of a low-spin iron(III) complex is [Fe(CN) 6] 3−. The cyanide ligands may easily be detached in [Fe(CN) 6] 3−, and hence this complex is poisonous, unlike the iron(II) complex [Fe(CN) 6] 4− found in Prussian blue, [16] which does not release hydrogen cyanide except when dilute acids are added. [17]
It is usually available as the salt potassium ferrocyanide, which has the formula K 4 Fe(CN) 6. [Fe(CN) 6] 4− is a diamagnetic species, featuring low-spin iron(II) center in an octahedral ligand environment. Although many salts of cyanide are highly toxic, ferro- and ferricyanides are less toxic because they tend not to release free cyanide. [1]
For example, Prussian blue is an iron(II,III)–cyanide complex in which there is an iron(II) atom surrounded by six carbon atoms of six cyanide ligands bridged to an iron(III) atom by their nitrogen ends. In the Turnbull's blue preparation, an iron(II) solution is mixed with an iron(III) cyanide (c-linked) complex. An electron-transfer ...
Cyanometallates or cyanometalates are a class of coordination compounds, most often consisting only of cyanide ligands. [1] Most are anions. Cyanide is a highly basic and small ligand, hence it readily saturates the coordination sphere of metal ions.
Among the most toxic cyanides are hydrogen cyanide (HCN), sodium cyanide (NaCN), potassium cyanide (KCN), and calcium cyanide (Ca(CN) 2). The cyanide anion is an inhibitor of the enzyme cytochrome c oxidase (also known as aa 3 ), the fourth complex of the electron transport chain found in the inner membrane of the mitochondria of eukaryotic cells.
Most of the iron in the crust is combined with various other elements to form many iron minerals. An important class is the iron oxide minerals such as hematite (Fe 2 O 3), magnetite (Fe 3 O 4), and siderite (FeCO 3), which are the major ores of iron. Many igneous rocks also contain the sulfide minerals pyrrhotite and pentlandite.