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When the density of electrons in solids is not in equilibrium, diffusion of electrons occurs. For example, when a bias is applied to two ends of a chunk of semiconductor, or a light shines on one end (see right figure), electrons diffuse from high density regions (center) to low density regions (two ends), forming a gradient of electron density.
Contrary to brownian motion, which is the diffusion of a single particle, interactions between particles may have to be considered, unless the particles form an ideal mix with their solvent (ideal mix conditions correspond to the case where the interactions between the solvent and particles are identical to the interactions between particles ...
In the crystal solid state, diffusion within the crystal lattice occurs by either interstitial or substitutional mechanisms and is referred to as lattice diffusion. [1] In interstitial lattice diffusion, a diffusant (such as C in an iron alloy), will diffuse in between the lattice structure of another crystalline element.
It is notable that Fick's work primarily concerned diffusion in fluids, because at the time, diffusion in solids was not considered generally possible. [3] Today, Fick's laws form the core of our understanding of diffusion in solids, liquids, and gases (in the absence of bulk fluid motion in the latter two cases).
Tunneling diffusion is a particularly interesting example of an unconventional mechanism wherein hydrogen has been shown to diffuse on clean metal surfaces via the quantum tunneling effect. Various analytical tools may be used to elucidate surface diffusion mechanisms and rates, the most important of which are field ion microscopy and scanning ...
Diffuse reflection - Generally, when light strikes the surface of a (non-metallic and non-glassy) solid material, it bounces off in all directions due to multiple reflections by the microscopic irregularities inside the material (e.g., the grain boundaries of a polycrystalline material or the cell or fiber boundaries of an organic material ...
In physics and engineering, permeation (also called imbuing) is the penetration of a permeate (a fluid such as a liquid, gas, or vapor) through a solid.It is directly related to the concentration gradient of the permeate, a material's intrinsic permeability, and the materials' mass diffusivity. [1]
A diffusionless transformation, commonly known as displacive transformation, denotes solid-state alterations in crystal structures that do not hinge on the diffusion of atoms across extensive distances. Rather, these transformations manifest as a result of synchronized shifts in atomic positions, wherein atoms undergo displacements of distances ...