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An elimination reaction is a type of organic reaction in which two substituents are removed from a molecule in either a one- or two-step mechanism. [2] The one-step mechanism is known as the E2 reaction , and the two-step mechanism is known as the E1 reaction .
Substitution reactions in organic chemistry are classified either as electrophilic or nucleophilic depending upon the reagent involved, whether a reactive intermediate involved in the reaction is a carbocation, a carbanion or a free radical, and whether the substrate is aliphatic or aromatic. Detailed understanding of a reaction type helps to ...
In chemistry, solvolysis is a type of nucleophilic substitution (S N 1/S N 2) or elimination where the nucleophile is a solvent molecule. [1] Characteristic of S N 1 reactions, solvolysis of a chiral reactant affords the racemate.
Organic chemistry has a strong tradition of naming a specific reaction to its inventor or inventors and a long list of so-called named reactions exists, conservatively estimated at 1000. A very old named reaction is the Claisen rearrangement (1912) and a recent named reaction is the Bingel reaction (1993).
In organic chemistry, the E i mechanism (Elimination Internal/Intramolecular), also known as a thermal syn elimination or a pericyclic syn elimination, is a special type of elimination reaction in which two vicinal (adjacent) substituents on an alkane framework leave simultaneously via a cyclic transition state to form an alkene in a syn elimination. [1]
In organic chemistry, Zaytsev's rule (or Zaitsev's rule, Saytzeff's rule, Saytzev's rule) is an empirical rule for predicting the favored alkene product(s) in elimination reactions. While at the University of Kazan , Russian chemist Alexander Zaytsev studied a variety of different elimination reactions and observed a general trend in the ...
In chemistry, an addition-elimination reaction is a two-step reaction process of an addition reaction followed by an elimination reaction. This gives an overall effect of substitution, and is the mechanism of the common nucleophilic acyl substitution often seen with esters, amides, and related structures. [1]
Reductive elimination is an elementary step in organometallic chemistry in which the oxidation state of the metal center decreases while forming a new covalent bond between two ligands. It is the microscopic reverse of oxidative addition, and is often the product-forming step in many catalytic processes. Since oxidative addition and reductive ...
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