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John "Iron-Mad" Wilkinson (1728 – 14 July 1808) was an English industrialist who pioneered the manufacture of cast iron and the use of cast-iron goods during the Industrial Revolution. He was the inventor of a precision boring machine that could bore cast iron cylinders, such as cannon barrels [ 1 ] and piston cylinders used in the steam ...
A metal-phosphine complex is a coordination complex containing one or more phosphine ligands. Almost always, the phosphine is an organophosphine of the type R 3 P (R = alkyl, aryl). Metal phosphine complexes are useful in homogeneous catalysis .
Isaac Wilkinson (baptised 6 May 1695 - 31 January 1784) was an English industrialist, one of the founders of the iron industry and pioneer of the Industrial Revolution. However, his business ethics were precarious and his commercial affairs frequently chaotic.
The space to expand at Bersham had run out, and Wilkinson needed to move on. He bought a house and estate at nearby Brymbo and built a blast furnace there, at what would later become Brymbo Steelworks. John Wilkinson had fallen out with his brother William, who raised a small gang to destroy Bersham Ironworks.
Wilkinson's catalyst (chloridotris(triphenylphosphine)rhodium(I)) is a coordination complex of rhodium with the formula [RhCl(PPh 3) 3], where 'Ph' denotes a phenyl group. It is a red-brown colored solid that is soluble in hydrocarbon solvents such as benzene, and more so in tetrahydrofuran or chlorinated solvents such as dichloromethane .
Falling Creek Ironworks was the first iron production facility in North America. It was established by the Virginia Company of London in Henrico Cittie (sic) on Falling Creek near its confluence with the James River.
The works was founded by the pioneer industrialist John 'Iron Mad' Wilkinson.Wilkinson, who had owned the nearby Bersham Ironworks jointly with his brother William, purchased Brymbo Hall and its 500-acre estate from the Assheton-Smith family in 1792 for the sum of £14,000, some of which may have been lent by Boulton and Watt. [1]
The metal produced was considered to be the finest in South Wales. The Ironworks was established by John Guest and Isaac Wilkinson in 1763, but the venture was unsuccessful and transferred to Anthony Bacon in 1765. On his death in 1788, Richard Hill became the owner. Anthony Hill, [2] a later owner, adopted the Bessemer process. On his death in ...
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