Search results
Results from the WOW.Com Content Network
Dimethyl sulfide has a characteristic odor commonly described as cabbage-like.It becomes highly disagreeable at even quite low concentrations. Some reports claim that DMS has a low olfactory threshold that varies from 0.02 to 0.1 ppm [clarification needed] between different persons, but it has been suggested that the odor attributed to dimethyl sulfide may in fact be due to disulfides ...
Polyphenylene sulfide is a useful high temperature plastic. Coenzyme M, CH 3 SCH 2 CH 2 SO − 3, is the precursor to methane (i.e. natural gas) via the process of methanogenesis. Selected thioethers, from left: dimethylsulfide, coenzyme-M, the amino acid methionine, the vitamin biotin, and the engineering plastic polyphenylene sulfide.
DMSO reductase is a molybdenum-containing enzyme that catalyzes reduction of dimethyl sulfoxide (DMSO) to dimethyl sulfide (DMS). This enzyme serves as the terminal reductase under anaerobic conditions in some bacteria, with DMSO being the terminal electron acceptor. During the course of the reaction, the oxygen atom in DMSO is transferred to ...
Of the volatile by-products, dimethyl sulfide has a strong, pervasive odour and carbon monoxide is acutely toxic, so the reaction and the work-up needs to be performed in a fume hood. Dimethyl sulfide is a volatile liquid (B.P. 37 °C) with an unpleasant odour at even low concentrations. [8] [9] [10]
It is a weak acid, with a pK a of ~10.4, but is about a hundred thousand times more acidic than methanol. The colorless salt can be obtained in this way: CH 3 SH + CH 3 ONa → CH 3 SNa + CH 3 OH. The resulting thiolate anion is a strong nucleophile. It can be oxidized to dimethyl disulfide: 2CH 3 SH + [O] → CH 3 SSCH 3 + H 2 O
Acid-producing gasses are also created by biological processes that occur on the land, in wetlands, and in the oceans. The major biological source of sulfur compounds is dimethyl sulfide. Nitric acid in rainwater is an important source of fixed nitrogen for plant life, and is also produced by electrical activity in the atmosphere such as ...
Another volatile breakdown product is dimethyl sulfide (CH 3 SCH 3; DMS). There is evidence that DMS in seawater can be produced by cleavage of dissolved (extracellular) DMSP [7] [8] by the enzyme DMSP-lyase, although many non-marine species of bacteria convert methanethiol to DMS. [citation needed]
It is an adduct between borane molecule (BH 3) and dimethyl sulfide molecule (S(CH 3) 2). It is a complexed borane reagent that is used for hydroborations and reductions. The advantages of BMS over other borane reagents, such as borane-tetrahydrofuran, are its increased stability and higher solubility. [1]