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Explosives with negative or positive oxygen balance are commonly mixed with other energetic materials that are either oxygen positive or negative, respectively, to increase the explosive's power. For example, TNT is an oxygen negative explosive and is commonly mixed with oxygen positive energetic materials or fuels to increase its power. [3] [4]
Oxygen balance is an expression that is used to indicate the degree to which an explosive can be oxidized. If an explosive molecule contains just enough oxygen to convert all of its carbon to carbon dioxide, all of its hydrogen to water, and all of its metal to metal oxide with no excess, the molecule is said to have a zero oxygen balance.
Of greatest concern to the environment are secondary explosives, such as TNT, RDX, and HMX because they are produced and used in the greatest quantities. [2] Explosives and their residual post explosion products can partition between multiple environmental compartments including aquatic, soil, atmosphere, and the biosphere. [2] [3]
The limiting oxygen concentration (LOC), [1] also known as the minimum oxygen concentration (MOC), [2] is defined as the limiting concentration of oxygen below which combustion is not possible, independent of the concentration of fuel. It is expressed in units of volume percent of oxygen. The LOC varies with pressure and temperature.
The oxygen surplus of ammonium nitrate increases the energy release of TNT during detonation. Depending on the ratio of ingredients used, amatol leaves a residue of white or grey smoke after detonation. Amatol has a lower explosive velocity and correspondingly lower brisance than TNT but is cheaper because of the lower cost of ammonium nitrate.
An Oxyliquit, also called liquid air explosive or liquid oxygen explosive, is an explosive material which is a mixture of liquid oxygen (LOX) with a suitable fuel, such as carbon (as lampblack), or an organic chemical (e.g. a mixture of soot and naphthalene), wood meal, or aluminium powder or sponge. It is a class of Sprengel explosives.
A fuel–air explosive (FAE) device consists of a container of fuel and two separate explosive charges. After the munition is dropped or fired, the first explosive charge bursts open the container at a predetermined height and disperses the fuel in a cloud that mixes with atmospheric oxygen (the size of the cloud varies with the size of the ...
The chemistry of ANFO detonation is the reaction of ammonium nitrate with a long-chain alkane (C n H 2n+2) to form nitrogen, carbon dioxide, and steam.In an ideal stoichiometrically balanced reaction, ANFO is composed of about 94.5% AN and 5.5% FO by weight.