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In quantum mechanics, the position operator is the operator that corresponds to the position observable of a particle. When the position operator is considered with a wide enough domain (e.g. the space of tempered distributions), its eigenvalues are the possible position vectors of the particle. [1]
If one chooses the (generalized) eigenfunctions of the position operator as a set of basis functions, one speaks of a state as a wave function ψ(r) in position space. The familiar Schrödinger equation in terms of the position r is an example of quantum mechanics in the position representation. [5]
The momentum operator can be described as a symmetric (i.e. Hermitian), unbounded operator acting on a dense subspace of the quantum state space. If the operator acts on a (normalizable) quantum state then the operator is self-adjoint. In physics the term Hermitian often refers to both symmetric and self-adjoint operators. [7] [8]
The general form of wavefunction for a system of particles, each with position r i and z-component of spin s z i. Sums are over the discrete variable s z , integrals over continuous positions r . For clarity and brevity, the coordinates are collected into tuples, the indices label the particles (which cannot be done physically, but is ...
between the position operator x and momentum operator p x in the x direction of a point particle in one dimension, where [x, p x] = x p x − p x x is the commutator of x and p x , i is the imaginary unit, and ℏ is the reduced Planck constant h/2π, and is the unit operator. In general, position and momentum are vectors of operators and their ...
Since the angular momenta are quantum operators, they cannot be drawn as vectors like in classical mechanics. Nevertheless, it is common to depict them heuristically in this way. Depicted on the right is a set of states with quantum numbers ℓ = 2 {\displaystyle \ell =2} , and m ℓ = − 2 , − 1 , 0 , 1 , 2 {\displaystyle m_{\ell }=-2,-1,0 ...
The mathematical formulation of quantum mechanics (QM) is built upon the concept of an operator. Physical pure states in quantum mechanics are represented as unit-norm vectors (probabilities are normalized to one) in a special complex Hilbert space. Time evolution in this vector space is given by the application of the evolution operator.
Second quantization, also referred to as occupation number representation, is a formalism used to describe and analyze quantum many-body systems. In quantum field theory, it is known as canonical quantization, in which the fields (typically as the wave functions of matter) are thought of as field operators, in a manner similar to how the physical quantities (position, momentum, etc.) are ...